Organic Chemistry (OC): Recent submissions
Now showing items 81-100 of 316
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Synthetic investigations in terpenoids
The object of the present investigation is to develop a new strategy for the synthesis of 1-methylcyclohexa-1,3-diene derivatives, which are required for the construction of bicyclo[2.2.2]octane ring systems with bridgehead ... -
Studies in physical organic chemistry
The objects of these investigations are: (1) to study the preparation and properties of fulvenes possessing electron-withdrawing substituents at the C-6 position, in relation to the concept of anti-aromaticity, and (2) to ... -
Excited state behaviour of a,b – unsaturated thiones
The thesis entitled “Excited State Behaviour of ?,?-Unsaturated Thiones” consists of six chapters. Chapter I provides a brief introduction to the work presented in this thesis. Chapters II–V describe the photophysical and ... -
synthesis of some naturally occurring sesquiterpenes
Syntheses of Some Naturally Occurring Sesquiterpenes” consists of six chapters. Chapter 1 describes the first total syntheses of marmelerin (10) (isolated from Croton sonderianus Muell. Arg.), its positional isomer 12, and ... -
Synthesis and reactions of oxygen and nitrogen heterocycles..
The thesis is entitled “Synthesis and Reactions of Oxygen and Nitrogen Heterocycles” and is presented in five chapters. Chapter I deals with the synthesis of spironaphthalenones (1b) and (1c). 4-Methyl-2-naphthol was ... -
Acid catalysed cyclisation of steroidal seco-diones-total synthesis of racemic copacamphor & their Ylangocamphor & their G-homologues..
The thesis entitled “Acid-Catalysed Cyclisation of Steroidal Seco-Diones – Total Synthesis of Racemic Copacamphor and Ylangocamphor and Their C?-Homologues” consists of three chapters. The bicyclo[3.2.1]octane ring system ... -
Studies on enzyme models.
The thesis entitled "Studies on Enzyme Models" is divided into three chapters. The first chapter deals with a general introduction on the mechanism of enzyme action and study of enzyme models mimicking some enzymes. The ... -
studies in opium alkaloids
The thesis entitled "STUDIES IN OPIUM ALKALOIDS: (i) SYNTHETIC UTILITY OF AMINE QUATERNIZATION (ii) MICROBIAL TRANSFORMATIONS OF MORPHINE" consists of four chapters. CHAPTER 1: CONVENIENT METHOD FOR REPLACEMENT OF TERTIARY ... -
Synthetic studies in natural products
The thesis entitled "Synthetic Studies in Natural Products (Terpenes & Lignans)" is divided into three parts consisting of nine chapters. Chapter 1 gives a review of the chemistry of aromatic hemiterpenoids of 2,2-dimethylchromene ... -
Studies on synthetic drugs : Investigations on synthetic estrogens
PART I Section A After briefly reviewing the work on synthetic estrogens, the various methods for the synthesis of 2-methyl-2-carbomethoxy-5-(p-methoxyphenyl)-cyclohexanone are detailed. This ketone has been synthesized ... -
Synthesis and Self-Assembly Studies of Carbohydrate-Conjugated Oligo-p-Phenylenes
The structural diversity of carbohydrate derivatives is amplified further by their strong tendency to self-assemble in aq. solutions, provided the molecular constitution and environmental conditions favor. Glycostructures ... -
Design, Synthesis and Binding of Hydrogen Bond Surrogate (HBS) stabilized Helicomimics with Biorelevant DNA Transcription Factor Domains and Proteins
Although all cells share the same genome, their diverse functions arise from differential gene expression, which governs cell fate and activity. Dysregulation of this transcriptional machinery leads to diseases, highlighting ... -
Photoluminescent Lanthanocholate Gel-Based Sensors for Human Well-Being
Lanthanide-based luminescent materials have emerged as highly promising in biosensing, primarily owing to the long lifetimes of lanthanides, which enable the efficient elimination of background signals during time-delayed ... -
NanoPhotoCatalysis: A New Dimension in Synthetic Chemistry
Photocatalysis has emerged as a powerful tool in recent years to drive chemical transformations via electron/energy transfer, allowing access to several unstable or high energy intermediates. Thus, the design and ... -
Iridium-Catalyzed Regio- and Enantioselective Alkylation of Unsaturated Carbonyls
This thesis, entitled “Iridium-Catalyzed Regio- and Enantioselective Alkylation of Unsaturated Carbonyls” primarily deals with the development of various catalytic regio-, diastereo- and enantioselective allylic and allenylic ... -
Iridium-Catalyzed Enantioselective Alkylation of Enols and Their Surrogates
This thesis, entitled “Iridium-Catalyzed Enantioselective Alkylation of Enols and their Surrogates” is divided into four chapters. In Chapter 1, the examples of the utilization of vinyl azide as amide and ketone enolate ... -
Understanding the Mechanism and Stereoselectivity of Fe-catalyzed Carbene Insertion Reactions using Computational Tools
Transition-metal and enzyme-catalyzed carbene insertion reactions are key methods for constructing C–X (X=N, O, S) and C–C bonds, primarily using catalysts such as Rh, Pd, Au, Cu, and Fe. While most of these give high ... -
Breaking Symmetry – Organocatalytic Enantioselective Synthesis of Natural and Unnatural Ladderanes
Architecturally unique compounds produced by nature have remained a source of inspiration for organic chemists. Ladderane phospholipids (such as [5][3]PC and [3][3]PC), isolated in the year 2002 from anaerobic ammonium oxidizing ... -
N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of C-O Axially Chiral Diaryl Ethers, Tricyclic Lactones and Lactams
N-heterocyclic carbene (NHC)-catalyzed transformations with distinctive activation modes allow the facile synthesis of atropoisomers. In this context, we have demonstrated the NHC-catalyzed synthesis of axially chiral diaryl ... -
Delayed Luminescent Materials: Development and Exploration of Applications
Delayed luminescence (DL) refers to light emission that persists after the excitation source is removed. Differing from conventional fluorescence, DL has a considerably longer lifetime attributable to the slow exciton ...