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Catalytic Studies with Ru and Ir Half-sandwich Complexes Bearing NHC Ligands
The thesis describes the study of arene-tethered and untethered Ru half-sandwich complexes as catalysts in the addition of hydroelements (E‒H, E = H, B, Si) across unsaturated C-C, C-N and C-O bonds and transfer hydrogenation ...
Vanadium Complexes for DNA Crosslinking and Photodynamic Applications
The present thesis work deals with the studies involving synthesis of vanadium-based complexes as photoactivated chemotherapeutic as well a photodynamic therapeutic agent. Their interactions with DNA, as double-stranded ...
Rotational Spectroscopic and Computational Studies on Inter/Intramolecular Bonding
The importance of non-covalent interactions cannot be undermined, as it permeates nearly every sphere of chemistry. The hydrogen bond is the most well-known and ubiquitous non-covalent interaction. In recent times similar ...
Design, Synthesis and Optical Characterization of Thiophene Based Luminophore
We successfully designed and synthesized a series of thiophene based luminophores. We were able to modulate the optical band gap of these luminophores by systematically fine-tuning the chemical structure of these compounds. ...
Nonequilibrium dynamics and thermodynamics of some single-particle activity-induced diffusive systems
In the mesoscopic world, diffusion is a ubiquitous process and it is usually explained by the
Einstein’s theory of Brownian motion (BM). However, in the biological systems, some peculiar
dynamical behaviors are observed ...
Carbon aerogel supported first-row transition metal catalysts for methanolyis of ammonia borane
Ni-Ni3B, Co-B, and Co-Ni-B nanocomposites decorated on carbon aerogel were successfully synthesized by adopting the solution impregnation method. The nanocomposites were characterized by powder XRD, transmission electron ...
Vibrational Spectroscopic studies of Dynamics of BSA unfolding, Lysozyme-Ethanol interaction and Tissue Imaging
Vibrational spectroscopy has served as a powerful tool for understanding various structural properties of the molecules since decades. In the recent years, it has also emerged as an invaluable tool in understanding various ...
Syntheses and Structure Elucidations of Co-crystal with Nicotinamide Co-former
Abstract :
Co-crystals consist of two or more components that form a unique crystalline structure having unique properties. The components interact via non-covalent, ionic interaction, van der Waals interactions and π-π ...
Organic Transformations in the Confined Cavity of Self-Assembled Pd(II) Molecular Containers
Biological systems utilize its extraordinary ability to develop complex and functional molecular
assemblies employing reversible non-covalent interactions. These natural aesthetic examples
motivated synthetic chemists ...
Thermal and Femtosecond Laser-Induced CO2-Surface Chemistry on Supported Iron-Oxide Based Nanoparticle Surfaces under UHV
The thesis has been presented in two parts. The 1st part of the thesis focuses on the
fundamental understanding of room temperature CO2 adsorption on iron-oxide based NP
surfaces. The 2nd part describes the understanding ...