Inorganic and Physical Chemistry (IPC)
Recent Submissions
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Synthesis, spectra and structure of hydrazinium metal chloride and thiocynate complexes.
Coordination compounds containing positively charged ligands occur rather seldom in marked contrast with neutral and negatively charged ligands. The presence of positive charge in the vicinity of a potential donor atom in ... -
Contributions to the chemistry of phosphorus fluorine compounds and a few complex fluorides
The thesis incorporates the results of the investigations on (1) Oxidative reactions of sulphur trioxide, iodine monochloride and nitryl chloride with phosphorus trifluoride and thiophosphoryl fluoride, (2) Reactions of ... -
Studies on fine particle alpha alumina and related oxides prepared by a novel combustion process
Aluminous oxides form one of the major and most important classes among oxide ceramics. Their technological applications as refractories, abrasives, cutting tools (?-Al?O?, MgAl?O?), high alumina cement (CaAl?O?), catalysts ... -
35 CI NQR instrumentation and investigation of some chloropyridinols and chloropyridine-N-Oxides
The detection of quadrupole resonance absorption requires application of a radio frequency magnetic field H? of suitable frequency. The rf field H? should be such that ?H?T?T? ? 1 to avoid saturation, but not be so small ... -
Complex plane and DC polarographic studies of lead (11) ethanolamine (mono-D1 and TR1-) systems
A detailed investigation on the polarographic (d.c. and complex plane) behavior of lead ion in sodium perchlorate, potassium nitrate, potassium chloride, ethanolammonium (mono-, di-, and tri-) perchlorates and the respective ... -
Kinetics and mechanism of the transient behaviour of magnesium anodes
The main objective of the present investigation is to study the mechanism of delayed dissolution of magnesium anodes during discharge of magnesium dry cells. A supplementary part of the work is devoted to the development ... -
Magnetic and spectroscopic investigations of iron and other ..... Ligands
The complexes of a new ligand, 2-thioacetamido thiazole (TATZ) with halide and nitrate salts of Fe(II), Ni(II), Cu(I,II), Zn(II), Cd(II) and Hg(II) have been synthesized. The compounds have the general formula, M(TATZ)?·nH?O ... -
INVESTIGATIONS ON Positive Temperature Coefficient of Resistance OF POLYCRYSTALLINE BARIUM TITANATE
The way similar to monomerisation or at higher temperatures. CD studies indicated no major change in the secondary structure of the proteins of lipovitellins during chloroform absorption. The interaction of Ca²? and Na? ... -
Studies on some bildegradable polymers
The graft copolymerization of methyl acrylate, ethyl acrylate and acrylonitrile onto gelatin in aqueous medium was necessarily heterogeneous and was not simple enough for studying the kinetic and mechanistic aspects of the ... -
Studies in the polarographic (D.C and A.C) behaviour of amino acid complexes of vanadium
As already pointed out the chief techniques employed in the present work are the classical d.c. polarography and its variation the a.c. polarography. It is the complementary use of these two techniques that has been helpful ... -
Effect of prior treatment on the chemical reactivity of inorganic perchlorates Ph.D. Thesis
The effect of mechanical and thermal pre-treatment on the chemical reactivity of inorganic perchlorates has been studied. The perchlorate system was chosen in view of its importance as a source of oxygen in solid rocket ... -
Palladium complexes of P,P-, P,N- and P,S- donor ligands based on the P-N-P motif
The diphosphazane ligands of the type Ph?P(E)N(R)P(E?)Ph? (1–5) exhibit diverse palladium–allyl chemistry, including various fluxional processes in solution. The symmetrical ligands Ph?PN(CHMe?)PPh? (1) and Ph?P(S)N(CHMe?)P(S)Ph? ... -
Theoretical studies on intermolecular hydrogen transfer reactions
Overview of Intermolecular Hydrogen Transfer Reactions This thesis explores various features of intermolecular hydrogen transfer reactions using theoretical methods such as ab initio calculations and analytical models. Key ... -
Lanthanide and actinide complexes of diphosphazane dioxides and lanthanide complexes of amino acids and peptides
The chemistry of f-block elements is currently undergoing rapid developments, and a rich and diverse chemistry is emerging because of its various applications (e.g., MOCVD precursors, MRI contrast agents). In addition, ... -
Theoretical studies on hydrogen transfer reactions
The present analysis reveals the following features: (i) The calculated activation barriers via both configuration mixing approach (using equations 2.1–2.4) and quantum chemical methods (using MNDO/RHF/CI and AM1/RHF/CI) ...

