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Room Temperature Molten Liquids Based On Amides : Electrolytes For Rechargeable Batteries, Capacitors And Medium For Nanostructures
(2011-01-10)
Room temperature molten liquids are proposed to be good alternates for volatile and harmful organic compounds. They are useful in varied areas of applications ranging from synthesis, catalysis to energy storage molten ...
Synthetic Antioxidants : Structure-Activity Correlation Studies Of Glutathione Peroxidase Mimics And Peroxynitrite Scavengers
(2011-01-11)
Reactive oxygen species (ROS) such as superoxide radical anion (O2•¯), hydroxylradical (OH•), hydrogen peroxide (H2O2) and peroxynitrite (ONOO-) that are produced during the metabolism of oxygen under oxidative stress in ...
Reductive And Metathetic Coupling Reactions Mediated By Group (IV) Metal Alkoxides
(2010-10-19)
Several organic transformations are mediated by group(IV) metal alkoxides. The reactivity is based on the basic nature of alkoxide group, Lewis acidic nature of the group(IV) metals, insertion of unsaturated molecules into ...
Studies Of MnO2 As Active Material For Electrochemical Supercapacitors
(2010-11-02)
Electrical double-layer formed at the interface between an electrode and an electrolyte has been a topic of innumerable studies. The electrical interface plays a crucial role in kinetics, mechanisms and applications in ...
Time Resolved Resonance Raman Spectroscopic Studies Of Heterocyclic Aromatic Systems
(2012-04-23)
Benzophenone (BP) and substituted BPs constitute a major class of aromatic ketones and are of potential interest in various areas of excited state solution phase photochemistry and photobiology. High triplet state energy, ...
Chiral Bisphosphinites For Asymmetric Catalysis
(2010-07-21)
Chiral bisphosphinites are well-documented alternatives for chiral bisphosphines as ligands that can be exploited in various asymmpetric syntheses. Particularly, vicinal biarylphophinite ligands give a seven membered chelate ...
A Study on Digestive Ripening Mediated Size and Structure Control in Nanoparticles Prepared by Solvated Metal Atom Dispersion Method
(2017-12-16)
Recent advancements in nanotechnology and emerging applications of nanomaterials in various fields have stimulated interest in fundamental scientific research dealing with the size and structure controlled synthesis of ...
Mapping The Reaction Coordinate For The Oxidative Addition Of Molecular Hydrogen To A Metal Center
(2010-07-15)
The binding of molecular hydrogen to a metal center leads to the elongation of the H−H bond and subsequently to its cleavage along the reaction coordinate for the oxidative addition of H2. There has been considerable ...
Understanding Solvent Effect On Triplet State Structure Of Thioxanthone And Its Derivatives Using Time-Resolved Resonance Raman Spectroscopy
(2014-05-01)
It has long been recognized that course and efficiency of a chemical reaction is largely mediated by the short-lived transient species (excited state or radicals) which are formed as reactive intermediates during a chemical ...
Nature Of Solute-Solvent Interaction : Effect Of Solvent Polarity On Excited State Structure Of 2,2,2-Trifluroacetophenone And Effect Of Hydrogen Bonding In Hydrated Electron Absorption Spectrum
(2009-09-02)
In solution, the environment around the solute is determined solely by the solvent molecules, which are present closer to the solute. This interaction between solute and solvent shell is very crucial for equilibrium structure ...