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Studies On Lanthanide Complexes Showing Photo-activated DNA Cleavage And Anticancer Activity
(2015-01-08)
This thesis work deals with different aspects of the chemistry of La(III) and Gd(III) complexes, their interaction with DNA and proteins, photo-induced cleavage of double-stranded DNA, photocytotoxic effect on cancer cells, ...
Self-Selection Of Discrete Molecular Architectures In Coordination-Driven Self-Assembly
(2016-10-20)
Self–assembly has long been attracting chemists’ attention because it can yield fascinating supramolecular architectures in a single step. More precisely, metal–ligand coordination–driven self–assembly has stood out as an ...
Synthesis, Structural Elucidation and Anticancer Activity Studies on Metal Complexes of Nucleic Acid Constituents and their Derivatives
(2018-01-04)
Metal-nucleic acid interaction studies have been gaining attention due to their biological and chemical importance. Nucleic acids are negatively charged bio-polymers and neutralization of their negative charge is essential ...
Palladium and Nickel Chalcogenides as Electrocatalysts
(2017-12-02)
In recent years, there has been an increasing interest on renewable energy sources as substitute to fossil fuels. Among various processes of energy generation, electrochemical methods such as storage and conversion systems, ...
High Capacity Porous Electrode Materials of Li-ion Batteries
(2017-12-12)
Lithium-ion battery is attractive for various applications because of its high energy density. The performance of Li-ion battery is influenced by several properties of the electrode materials such as particle size, surface ...
A Computational Study of C-H Binding, C-H Activation and Fluxional Processes of d6 Half- Sandwich Complexes
(2017-11-24)
Significant developments have been made in the field of C–H activation. However, various disadvantages, mainly low reactivity and selectivity, limit their usage in large-scale synthesis. It is crucial to understand the ...
The Effect of Substituents and Solvents on the Deiodination Reactions of Thyroid Hormones by Iodothyronine Deiodinase Mimics
(2017-12-07)
Thyroid hormones (THs; T4 and T3), secreted from thyroid gland, play an important role in human growth and development. T3 (3,5,3′-triiodothyronine) is the active hormone and the conversion of T4 (3,3′,5,5′-tetraiodothyronine) ...
Itaconate-based Periodically Grafted Polyesters
(2017-12-03)
Block copolymers can self-assemble into a variety of periodic nanostructures and therefore, are promising candidates for a diverse range of applications. While self-assembly of block copolymers has been widely studied and ...
Mechanistic Investigation of Metal Promoted Nucleophilic Additions
(2017-11-30)
Nucleophilic additions are an important class of reactions in the preparation of several organic compounds. Metals facilitate nucleophilic additions in many cases. The present work Mechanistic Investigation of Metal Promoted ...
Studies On The Photocytotoxic Effect Of Ferrocene-Conjugated Copper(II) Complexes
(2016-04-29)
The present thesis deals with different aspects of the chemistry and photo-biology of various ferrocene-conjugated metal complexes, their interaction with double helical DNA, DNA photocleavage and photo-enhanced cytotoxicity ...