Division of Chemical Sciences: Recent submissions
Now showing items 581-600 of 969
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Stereochemical And Synthetic Investigations
(2017-05-25)PART I RESOLUTION AND DESYMMETRISATION Chapter I. ‘A Novel Racemate Resolution’. This describes a novel resolution strategy as applied to racemic α-amino acids in the solid state. The strategy is based on the possibility ... -
Serendipitous Assembly Of 3d Metal-Ion Polyclusters : Structures, Magnetic Behavior And Theoretical Studies
(2017-02-22)The last two decades have seen extensive growth in interest in metal-ion assemblies, especially for building new polynuclear exchange-coupled magnetic systems. However, the concept of designing polynuclear extended structures ... -
Phase Transformation Behavior Of Embedded Bimetallic Nanoscaled Alloy Particles In Immiscible Matrices
(2017-02-16)The aim of the present thesis is to understand the phase transformation behavior of embedded alloy nanoparticles embedded in immiscible matrices. Embedded alloy inclusions have been dispersed in immiscible matrix via rapid ... -
Phase Transition In Soft-Condensed Matter Fluids And Contribution To Enzyme Kinetics Including Kinetic Proofreading
(2016-11-16)The thesis involves computer simulation and theoretical studies of phase transition in soft-condensed matter systems and theoretical understanding of enzyme kinetics along with kinetic proofreading of tRNA-aminoacylation ... -
Enantiospecific Synthesis Of Silphiperfolane, Basmane And Fusicoccanes
(2016-10-20)Nature’s expertise and virtuosity in creating a phenomenal array of carbocyclic frameworks finds its full expression in the terpenoid group of natural products. The total synthesis of natural products frequently provided ... -
Functionalized Hyperbranched Polymers And Nonionenes
(2016-10-20)In 1980’s a new class of material named as dendrimer became popular both in the field of polymer science and engineering. Dendrimer is an example of symmetric, highly branched three dimensional globular nano-object. It ... -
Self-Selection Of Discrete Molecular Architectures In Coordination-Driven Self-Assembly
(2016-10-20)Self–assembly has long been attracting chemists’ attention because it can yield fascinating supramolecular architectures in a single step. More precisely, metal–ligand coordination–driven self–assembly has stood out as an ... -
Electronic Structure And Bonding In Metallaboranes And Main Group Compounds
(2016-05-04)This thesis entitled “Electronic Structure and Bonding in Metallaboranes and Main Group Compounds” consists of five chapters. Chapter 1 gives an exposition of concepts and techniques used in understanding the electronic ... -
Studies On The Photocytotoxic Effect Of Ferrocene-Conjugated Copper(II) Complexes
(2016-04-29)The present thesis deals with different aspects of the chemistry and photo-biology of various ferrocene-conjugated metal complexes, their interaction with double helical DNA, DNA photocleavage and photo-enhanced cytotoxicity ... -
Group III-Nitride Epitaxial Heterostructures By Plasma-Assisted Molecular Beam Epitaxy
(2016-04-18)Group III-nitride semiconductors have received much research attention and witnessed a significant development due to their ample applications in solid-state lighting and high-power/high-frequency electronics. Numerous ... -
Bile Acid Based Supramolecular Gels, Semiconductor Nanocrystals And Soft Hybrid Materials
(2016-04-12)Chapter 1. General Introduction This chapter gives an introduction to supramolecular organo/hydrogels and the related bile acid chemistry touching upon the gelation properties of the bile acid derivatives. Diverse ... -
New Supramolecular Ion Sensing Probes And Their Application In The Detection Of Environmentally Relevant Ions
(2016-03-04)The thesis entitled “New Supramolecular Ion Sensing Probes and their Application in the Detection of Environmentally Relevant Ions” deals with the design and synthesis of several small molecular probes which can specifically ... -
Design And Access To Disallowed And Unusual Conformers Of Peptides In Crystals And In Solution : Structural Consequences Of The Imidate And Thioimidate Isosteres For The Peptide Bond
(2016-03-04)This thesis entitled “Design and Access to Disallowed and Unusual Conformers of Peptides in Crystals and in Solution: Structural Consequences of the Imidate and Thioimidate Isosteres for the Peptide bond” is divided into ... -
Ultrafast Raman Loss Spectroscopy (URLS) : Understanding Resonant Excitation Response And Linewidth Changes
(2016-02-25)Raman spectroscopy involves change in the polarizability of the molecular system on excitation and is based on scattering process. Spontaneous Raman scattering is a two photon process, in which the input light initiates ... -
Targeting Cancer Cells And Live Cell Imaging Using Bis(thiosemicarbazone) Complexes Of Copper And Zinc
(2016-02-25)Transition metal bis(thiosemicarbazone) complexes have been of great interest in the last five decades. One of the most striking features of these complexes is that they possess a wide range of biological properties including ... -
Design And Development Of Synthetic Methods Using Metal-Mediated And Metal Free Redox Reactions : Novel C-H Activations, Reductions And Oxidative Transformations
(2016-02-16)The thesis entitled “Design and Development of Synthetic Methods using Metal-mediated and Metal-free Redox Reactions: Novel C-H Activations, Reductions and Oxidative Transformations” is presented in 4 chapters Chapter ... -
Studies On 2,3-Unsaturated Sugars : Reactivity Switching, Rearrangements And Conjugate Additions
(2015-12-21)Unsaturated sugars constitute as an important category of carbohydrate precursors in synthesis. Specifically, 1,2- and 2,3-unsaturated glycosides are excellent intermediates to derivatize monosaccharides and as building ... -
Investigation On Ag And ZnO Based Nanohybrids As Bactericides For The Purification Of Water And Elucidation Of Possible Mechanisms For Their Bio-activity
(2015-12-02)Chapter I: This chapter briefly gives an introduction about microorganisms, their varieties, growth, reproduction etc. In particular, about bacterial function. A sincere attempt is made to review this briefly, including ... -
Self-Assembly Of Functional Supramolecular Architectures via Metal-Ligand Coordination
(2015-09-09)Over the past few decades, supramolecular self-assembly has become an alternative synthetic tool for constructing targeted discrete molecular architectures. Among various interactions, metal-ligand coordination has attracted ... -
Electrochemical Detection Of Proteins : Myoglobin As A Case Study
(2015-09-08)An effective electrochemical sensor for myoglobin (Myb) detection was developed using a simple procedure of denaturing the protein with guanidine hydrochloride and detecting the released heme group by cyclic voltammetry. ...