| dc.contributor.advisor | Viswanath,D S | |
| dc.contributor.author | Sundaram, S | |
| dc.date.accessioned | 2026-02-09T10:58:34Z | |
| dc.date.available | 2026-02-09T10:58:34Z | |
| dc.date.submitted | 1976 | |
| dc.identifier.uri | https://etd.iisc.ac.in/handle/2005/8536 | |
| dc.description.abstract | The thesis embodies experimental data on
(i) vapour pressure,
(ii) vapour–liquid equilibria,
(iii) heats of mixing at 25 and 35°C, and
(iv) latent heats of vaporization
for the systems toluene and chloroethanes.
Vapour–liquid equilibrium data have been checked for their consistency by several methods.
The vapour?phase non?ideality has been corrected using virial equation of state truncated at the second virial coefficient. The second and third virial coefficients have been calculated using a three?parameter potential energy function.
Latent heats of vaporization calculated using rigorous thermodynamic relations have been compared with experimental data. | |
| dc.language.iso | en_US | |
| dc.relation.ispartofseries | T01341 | |
| dc.rights | I grant Indian Institute of Science the right to archive and to make available my thesis or dissertation in whole or in part in all forms of media, now hereafter known. I retain all proprietary rights, such as patent rights. I also retain the right to use in future works (such as articles or books) all or part of this thesis or dissertation | |
| dc.subject | Vapour–liquid equilibrium | |
| dc.subject | Virial coefficients | |
| dc.subject | Latent heat of vaporization | |
| dc.title | Thermodynamic properties of toluene chloroethane systems | |
| dc.type | Thesis | |
| dc.degree.level | Doctoral | |
| dc.degree.grantor | Indian Institute of Science | |
| dc.degree.discipline | Engineering | |