| dc.contributor.advisor | Prabhu, K R | |
| dc.contributor.author | Rao, Santhosh | |
| dc.date.accessioned | 2021-09-22T09:19:04Z | |
| dc.date.available | 2021-09-22T09:19:04Z | |
| dc.date.submitted | 2018 | |
| dc.identifier.uri | https://etd.iisc.ac.in/handle/2005/5327 | |
| dc.description.abstract | The thesis presents an unconventional approach for the molecular construction using carbenes as the carbon source, and water as the hydrogen source. A gold-catalyst has been used to transfer the carbenes to effect [2,3]-sigmatropic rearrangement; and tris(pentafluorophenyl)borane-catalyst for the C-C bond functionalization and carbonate transfer reactions. On the other hand, a Pd-catalyzed stereodivergent reduction of alkynes has been achieved using water. The mechanistic details of the hydrogenation have also been probed, and the derived understanding has been applied to construct C-C bonds | en_US |
| dc.language.iso | en_US | en_US |
| dc.relation.ispartofseries | ;G29446 | |
| dc.rights | I grant Indian Institute of Science the right to archive and to make available my thesis or dissertation in whole or in part in all forms of media, now hereafter known. I retain all proprietary rights, such as patent rights. I also retain the right to use in future works (such as articles or books) all or part
of this thesis or dissertation | en_US |
| dc.subject | carbenes | en_US |
| dc.subject | hydrogenation | en_US |
| dc.subject | C-C bonds | en_US |
| dc.subject.classification | Research Subject Categories::NATURAL SCIENCES::Chemistry::Organic chemistry | en_US |
| dc.title | Molecular Construction Using Carbene and Diboron Systems: Catalytic Transformation of C-C and C-Hetero Atom Bonds | en_US |
| dc.type | Thesis | en_US |
| dc.degree.name | PhD | en_US |
| dc.degree.level | Doctoral | en_US |
| dc.degree.grantor | Indian Institute of Science | en_US |
| dc.degree.discipline | Faculty of Science | en_US |
