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dc.contributor.advisorPrabhu, K R
dc.contributor.authorRao, Santhosh
dc.date.accessioned2021-09-22T09:19:04Z
dc.date.available2021-09-22T09:19:04Z
dc.date.submitted2018
dc.identifier.urihttps://etd.iisc.ac.in/handle/2005/5327
dc.description.abstractThe thesis presents an unconventional approach for the molecular construction using carbenes as the carbon source, and water as the hydrogen source. A gold-catalyst has been used to transfer the carbenes to effect [2,3]-sigmatropic rearrangement; and tris(pentafluorophenyl)borane-catalyst for the C-C bond functionalization and carbonate transfer reactions. On the other hand, a Pd-catalyzed stereodivergent reduction of alkynes has been achieved using water. The mechanistic details of the hydrogenation have also been probed, and the derived understanding has been applied to construct C-C bondsen_US
dc.language.isoen_USen_US
dc.relation.ispartofseries;G29446
dc.rightsI grant Indian Institute of Science the right to archive and to make available my thesis or dissertation in whole or in part in all forms of media, now hereafter known. I retain all proprietary rights, such as patent rights. I also retain the right to use in future works (such as articles or books) all or part of this thesis or dissertationen_US
dc.subjectcarbenesen_US
dc.subjecthydrogenationen_US
dc.subjectC-C bondsen_US
dc.subject.classificationResearch Subject Categories::NATURAL SCIENCES::Chemistry::Organic chemistryen_US
dc.titleMolecular Construction Using Carbene and Diboron Systems: Catalytic Transformation of C-C and C-Hetero Atom Bondsen_US
dc.typeThesisen_US
dc.degree.namePhDen_US
dc.degree.levelDoctoralen_US
dc.degree.grantorIndian Institute of Scienceen_US
dc.degree.disciplineFaculty of Scienceen_US


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