| dc.contributor.advisor | Mukherjee, Santanu | |
| dc.contributor.author | Roy, Soumya Jyoti Singh | |
| dc.date.accessioned | 2019-09-27T10:03:02Z | |
| dc.date.available | 2019-09-27T10:03:02Z | |
| dc.date.submitted | 2017 | |
| dc.identifier.uri | https://etd.iisc.ac.in/handle/2005/4285 | |
| dc.description.abstract | In summary, we have developed a catalytic enantioselective desymmetrization of prochiral
1,3-dinitropropanes, which proceeds via enantiogroup differentiating allylic alkylation
reaction. Functionalized allylic carbonates were used as the allyl source and the densely
functionalized products consisting of two vicinal stereocenters were obtained through acyclic
stereocontrol generally with good to excellent diastereoselectivity (up to >20:1 dr) and superb
enantioselectivity (up to >99:1 er). The utility of the desymmetrized products was
demonstrated through synthetic manipulations leading to an alkylidene butyrolactam and a
unique dihydropyrazole derivative | |
| dc.language.iso | en_US | en_US |
| dc.relation.ispartofseries | G28643; | |
| dc.rights | I grant Indian Institute of Science the right to archive and to make available my thesis or dissertation in whole or in part in all forms of media, now hereafter known. I retain all proprietary rights, such as patent rights. I also retain the right to use in future works (such as articles or books) all or part
of this thesis or dissertation | en_US |
| dc.subject | Carbon-heteroatom Bond Forming Reactions | en_US |
| dc.subject | Allylic Alkylative Desymmetrization | en_US |
| dc.subject | Prochiral Dinitropropanes | en_US |
| dc.subject | Deconjugated Butyrolactams | en_US |
| dc.subject | Enantioselective Desymmetrization | en_US |
| dc.subject | Deconjugated Butyrolactam | en_US |
| dc.subject | Enantioselective Catalysis | en_US |
| dc.subject.classification | Organic Chemistry | en_US |
| dc.title | Catalytic Enantioselective Allylic Alkylative Desymmetrization, Carbon-Carbon and Carbon-Heteroatom Bond Forming Reactions | en_US |
| dc.type | Thesis | en_US |
| dc.degree.name | PhD | en_US |
| dc.degree.level | Doctoral | en_US |
| dc.degree.grantor | Indian Institute of Science | en_US |
| dc.degree.discipline | Faculty of Science | en_US |
