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C-H Bond Functionalization and Tandem Cyclization with Alkynoates and Maleimides Using Directing Group Strategy
The thesis presents manganese‒ and rhodium‒catalyzed C‒H bond activation and tandem cyclization reactions. These reactions lead to the construction of carbon‒carbon bonds using directing group strategy. The thesis is divided ...
Radical and Lewis Acid Mediated Syntheses of Panaginsene, Indole-Fused Azabicyclo[3.3.1]Nonane and Davanoids
The thesis contains radical and Lewis acid-mediated syntheses of panaginsene, indole-fused
azabicyclo[3.3.1]nonanes, and davanoids. The thesis includes three chapters; chapter-I
contains the total synthesis of panaginsene, ...
Diverse Applications of Luminescent Metallocholate Hydrogels
Supramolecular gels are soft materials consisting of a solid three-dimensional network with noncovalent interactions such as hydrophobic interactions, hydrogen bonding, cation-п, and п- п interactions. Due to their soft, ...
Total Synthesis of Piperidine and Pyrrolidine Alkaloids and Towards the Total Synthesis of Strychnine
Total synthesis of natural products is an important area of contemporary interest in synthetic
organic chemistry. Total synthesis of natural products serves as a platform for the development of
new synthetic strategies ...
Self-assembly of Luminescent Metal Nanoclusters, Supramolecular Bile salt based Gels and their Soft Nanocomposites
The thesis is based on the study of the self-assembly of multicolor luminescent nanoclusters,
bile salt derived supramolecular gels and soft hybrid gel-nano composites
Molecular Construction Using Carbene and Diboron Systems: Catalytic Transformation of C-C and C-Hetero Atom Bonds
The thesis presents an unconventional approach for the molecular construction using carbenes as the carbon source, and water as the hydrogen source. A gold-catalyst has been used to transfer the carbenes to effect ...
Synthesis and Studies of Covalent Polydiacetylene Glycopolymers as Scaffolds to Uncover Intricate Carbohydrate-Protein Interactions
Overall, the Thesis work establishes:
• Monomeric and multimeric ligand-lectin interactions occurring at cell surfaces that could be assessed using purified protein and cellular model system, namely, glycovesicles;
• ...
A Mitsunobu-Michael Reaction Sequence to N-Heterocyclic Variants and Ti(III)-Mediated Synthesis of Terpenoids and N-Fused Indoles
The research work delineates a flexible and novel route for the diastereoselective construction of diversely substituted N-heterocyclic variants as valuable scaffolds for natural products and pharmaceuticals, starting from ...
Bile Salts in Supramolecular Chemistry: Synthesis of Fluorescent Nanoclusters, Oxide Nanoflowers, and Anion Effect on Metallogels
In summary, we have explored an interesting pH-dependent sensitization of Tb(III) using methyl salicylate (MS) as a sensitizer in aqueous media. Methyl salicylate was found to be a specific sensitizer for Tb(III) but not ...
Properties and Applications of Metal Cholate Hydrogels
This thesis presents a detailed study on the unusual properties of silver cholate,
applications of lanthanide cholate gels, enhanced luminescence of lanthanides by water, and
the mechanism of formation of these gels. ...