Browsing Organic Chemistry (OC) by Subject "Asymmetric Catalysis"
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Asymmetric Catalysis, Transition metal catalysis, Allylation, Propargylic alkylation, Cooperative catalysis and nonadjacent stereocenter
Transition metal catalysis has transformed asymmetric synthesis by enabling precise control of stereocenters, essential for bioactive molecules. This thesis outlines a systematic investigation of stereochemical complexity ... -
Asymmetric Catalysis: From Atroposelective Organocatalysis to Iridium-Catalyzed Generation of Central Chirality
Thesis Abstract: This thesis, entitled as “Asymmetric Catalysis: From Atroposelective Organocatalysis to Iridium-Catalyzed Generation of Central Chirality” is divided into three chapters. Chapter 1, highlights the ... -
Iridium-Catalyzed Enantioselective Alkylation of Enols and Their Surrogates
This thesis, entitled “Iridium-Catalyzed Enantioselective Alkylation of Enols and their Surrogates” is divided into four chapters. In Chapter 1, the examples of the utilization of vinyl azide as amide and ketone enolate ... -
N-Heterocyclic Carbene (NHC)-Catalyzed Stereoselective Synthesis of Six-Membered Heterocycles and Carbocycles
N-Heterocyclic carbene (NHC) based catalysis is employed for the generation of α,β-unsaturated acylazoliums followed by their interception with various nucleophiles, the formal [3+3] annulation reactions for the construction ... -
Stereocontrol through Catalytic Enantioselective C(sp2)−H and C(sp3)−H Alkylation: From Bifunctional Organocatalysis to Iridium-Catalysis
This thesis, entitled “Stereocontrol through Catalytic Enantioselective C(sp2)−H and C(sp3)−H Alkylation: From Bifunctional Organocatalysis to Iridium-Catalysis” primarily deals with the development of various catalytic ... -
Total Synthesis of Bio-Active Macrolide Natural Products and Sulfinamide Based Ligands in Asymmetric Catalysis
(2018-07-18)The thesis entitled “Total synthesis of bio-active macrolide natural products and sulphonamide based ligands in asymmetric catalysis” is divided into two chapters. First chapter of the thesis describes the total synthesis ...