Browsing Inorganic and Physical Chemistry (IPC) by Title
Now showing items 254-273 of 535
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Palladium and Nickel Chalcogenides as Electrocatalysts
(2017-12-02)In recent years, there has been an increasing interest on renewable energy sources as substitute to fossil fuels. Among various processes of energy generation, electrochemical methods such as storage and conversion systems, ... -
Palladium complexes of P,P-, P,N- and P,S- donor ligands based on the P-N-P motif
The diphosphazane ligands of the type Ph?P(E)N(R)P(E?)Ph? (1–5) exhibit diverse palladium–allyl chemistry, including various fluxional processes in solution. The symmetrical ligands Ph?PN(CHMe?)PPh? (1) and Ph?P(S)N(CHMe?)P(S)Ph? ... -
Path Integral Approach to Levy Flights and Hindered Rotations
(2018-04-12)Path integral approaches have been widely used for long in both quantum mechanics as well as statistical mechanics. In addition to being a tool for obtaining the probability distributions of interest(wave functions in the ... -
Phosphorus(III) Ligands Based On The P-N-P Skeleton And Their Transition Metal Complexes
(2009-06-05)There is considerable current interest in the design and synthesis of new phosphorus ligands and their transition metal complexes in view of their potential applications in homogeneous catalysis. The present study is ... -
Photo-responsive Self-assembled Coordination Architectures and Their Applications
Development of nanomaterials that mimic enzyme-like catalytic activities (nanozymes) has drawn special attention in recent time. Nanozymes possess exclusive advantages over natural enzymes like high stability, large-scale ... -
Photocytotoxicity And DNA Cleavage Activity Of Metal Scorpionates And Terpyridine Complexes
(2011-08-22)Scorpionate and terpyridine ligands are of importance in inorganic chemistry for their metal-binding properties. Tris-pyrazolylborate (Scorpionate) ligands that show facial binding mode and steric protection have been ... -
Photodynamic Therapy and Cellular Imaging using Platinum(II) Conjugates of Boron-dipyrromethene and Curcumin
The present thesis portrays the rational design and successful synthesis of platinum(II) complexes for achieving photoactivated dual action anticancer properties. The research project centers on synthesis, comprehensive ... -
Photoelectrochemistry of polycrystalline SrTiO3 and BaTiO3 semiconductor electrodes
This thesis deals with the investigations on the photoelectrochemistry and photoelectrolysis of water, making use of polycrystalline semiconductor electrodes of BaTiO? and SrTiO? with a view to understand the effect of ... -
Physical adsorption from mixtures of gases-Thesis submitted for the Degree of Doctor of Philosophy In the faculty of Science
The thesis deals with a study of the adsorption from binary mixtures of gases on solid surfaces. A major part of the investigations is carried out on silica gel, while a part of the work consists of an investigation on ... -
Physico-chemical investigations on rare earth compounds
The work on the hydrolysis of lanthanum ion described in this thesis has revealed the existence of the following hydroxy complexes: LaOH²?, La(OH)??, La?OH³? and La?OH??. The various reactions that occur in this system ... -
Physico-chemical studies of vinyl polymers
The field of polymer science presents a number of problems for investigation both in the solid form and in solution. Of these, most interesting and important is the molecular weight, the size, and the shape of the polymer ... -
Physico-chemical studies on Deoxyoligoyuanlic acids and their complexes with Polyribocytidylic acids
Venom and spleen exonuclease are capable of cleaving guanosine oligonucleotides when they are not aggregated. At 22°C, in presence of sodium ions aggregation is rapid even at 0.5 × 10?? M concentration. On the other hand, ... -
Physico-chemical studies on the dilute solution propertie of random copolymers ofacrylonitirle.
The large values of ‘a’, the M.H. exponent, in good solvents for both St–M and MMA–AN suggest that these molecules are highly extended in solution. Application of the different theories to calculate the unperturbed dimensions ... -
Physicochemical, Electrical and Electrochemical Studies on Titanium Carbide-Based Nanostructures
(2018-04-03)Materials for studies related to nanoscience and nanotechnology have gained tremendous attention owing to their unique physical, chemical and electronic properties. Among various anisotropic nanostructures, one dimensional ... -
Physiocochemical investigations on urea-nitrate calcium phosphate system
The experimental results obtained in the present investigation clearly demonstrate that when urea nitrate is ground with tribasic calcium orthophosphate, a reaction takes place in the solid-state even at laboratory temperature ... -
Platinum(II) Complexes as Dual Action DNA Crosslinking & Photochemotherapeutic Agents
(2017-12-07)The thesis work delineates the rational design and successful syntheses of platinum (II) complexes for achieving light promoted dual action anticancer properties. The research work focuses on the syntheses, elaborate ...