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Homo-and Hetero-Metallic Supramolecular Assemblies : Synthesis, Structures and Characterization
(2018-04-03)
The work highlighted in this dissertation comprises of syntheses and characterizations of coordination driven supramolecular compounds. The synthesized complexes are characterized by IR spectroscopy, multinuclear NMR ...
Targeting Cancer Cells And Live Cell Imaging Using Bis(thiosemicarbazone) Complexes Of Copper And Zinc
(2016-02-25)
Transition metal bis(thiosemicarbazone) complexes have been of great interest in the last five decades. One of the most striking features of these complexes is that they possess a wide range of biological properties including ...
Studies On The Photocytotoxic Effect Of Ferrocene-Conjugated Copper(II) Complexes
(2016-04-29)
The present thesis deals with different aspects of the chemistry and photo-biology of various ferrocene-conjugated metal complexes, their interaction with double helical DNA, DNA photocleavage and photo-enhanced cytotoxicity ...
An Architectural Exploration in Coordination Driven Self-Assembly & Fluorescent Imidazolium Salts as Picric Acid Receptors
(2017-10-11)
Nature has always remained a constant source of inspiration for chemists for synthesizing natural products, mimicking enzymatic reactions or to construct molecular architectures resembling biological assemblies. With the ...
Serendipitous Assembly Of 3d Metal-Ion Polyclusters : Structures, Magnetic Behavior And Theoretical Studies
(2017-02-22)
The last two decades have seen extensive growth in interest in metal-ion assemblies, especially for building new polynuclear exchange-coupled magnetic systems. However, the concept of designing polynuclear extended structures ...
Mechanistic Insights Into Small Molecule (Amine-Boranes, Hydrogen, Methane, Formic Acid Carbon dioxide) Activation Using Electrophilic Ru(II)-Complexes
(2017-11-09)
Current fossil fuels (Coal and Petroleum) based economy is not sustainable in the long run because of its dwindling resources, and increasing concerns of climate change due to excessive carbon dioxide (CO2) emission. To ...
Synthesis of Metal and Metal Oxide Nanosponges for Hydrogen Storage and Catalytic Applications
(2017-11-28)
Nanoporous metal represents a particular form of a metal, which combines the characteristics of metals, such as good thermal and electrical conductivity, catalytic activity with the materials properties characteristic of ...
Influence of Ancillary Ligands in the Chemistry of Transition Metal σ-Complexes
(2017-09-27)
This thesis work is based on an investigation of intermediates involved in various metal mediated catalytic reactions such as hydrogenation, hydroboration, functionalization of methane etc. An intermediate dictates the ...
Organic Imine Cages : Self-Sorting and Application
(2017-11-14)
Biological systems have the incredible ability to accomplish uncommon chemical transformations with supreme delicacy. Many of those chemical transformations take place within the pocket of enzymes, which provide unique ...
Investigation Of Inorganic Nanomaterials & Polymer Films
(2014-07-30)
The thesis is divided into two parts. The first part deals with the research work carried out on the synthesis and chemical modification of nanomaterials whereas the second part describes the preparation and characterisation ...