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Rotational Spectroscopic And Ab Initio Studies On The Weakly Bound Complexes Containing 0-H...π And S-H...π Interactions
(2010-11-22)
Work reported in this thesis mainly comprises of the assignments and analysis of the rotational spectra and structures of three weakly bound complexes: C2H4•••H2S, C6H5CCH•••H2O and C6H5CCH•••H2S. All the data have been ...
Aspects Of The Chemistry Of Iron Complexes Showing DNA Photo-cleavage Activity
(2010-12-30)
The present thesis deals with different aspects of the chemistry of iron complexes, their interaction with DNA and photo-induced cleavage of double-stranded DNA.
Chapter I presents a general introduction on metal-based ...
Antioxidant Activity Of The Anti-Inflammatory Compound Ebselen And Its Analogues : Role Of Nonbonded Interactions
(2010-10-05)
Although considered as a poison for long time, the importance of selenium as an essential trace element is now well recognized. In proteins, the redox active selenium moiety is incorportated as selenocysteine (Sec), the ...
Computational Studies On Macropolyhedral Boranes And Metallaboranes
(2011-01-11)
The analysis of nature of bonding in non-classical structures is always an intriguing area of research. Typical examples of such systems are polyhedral boranes that exhibit fascinating cluster bonding where the traditional ...
Syntheses and Structure Elucidations of Ternary Metal (Cu/Co)Complexes with Nucleic Acid Constituents
(2018-05-07)
The thesis is divided into four chapters
Chapter 1 provides a brief introduction to the metal-nucleic acid interactions, the role of synthetic models to understand them with both solution (potentiometric) and solid state ...
Investigations on Azide Functional Polymers as Binders for Solid Propellants
(2018-05-09)
This thesis contains investigations in the area of polymers herein propellants binders are modified functionally to meet the requirements of future energetic propellants. Chapter 1 contains a broad introduction to the area ...
Nanoparticle Mediated Suppression of Protein Aggregation
(2018-05-11)
The increasing demands for biopharmaceuticals to treat different diseases have raised concerns about controlling the quality and efficacy of such pharmaceuticals. The design and formulation of a stable protein or peptide ...
Metallo-β-Lactamase, Phosphotriesterase And Their Functional Mimics
(2011-01-11)
Metallohydrolases with dinuclear-zinc active sites perform many important biological hydrolytic reactions on a variety of substrates. In this regard, metallo-β-lactamases (mβ1, class B) represent a unique subset of zine ...
Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes
(Indian Institute of Science, 2007-06-22)
The bite angle of a diphosphine ligand plays an important role in determining the reactivity of a transition metal complex. The coordinated dihydrogen on a transition metal center can be activated toward homolysis or ...
Theoretical Investigations Of Structure, Energy And Properties Of A Few Inorganic Compounds
(2010-08-11)
This thesis reports the theoretical investigations aimed at understanding the structure, stability and properties of a few inorganic compounds. The first chapter presents an introductory overview of the theories used to ...