Browsing Division of Chemical Sciences by Subject "Inorganic and Physical Chemistry"
Now showing items 21-40 of 41
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Itaconate-based Periodically Grafted Polyesters
(2017-12-03)Block copolymers can self-assemble into a variety of periodic nanostructures and therefore, are promising candidates for a diverse range of applications. While self-assembly of block copolymers has been widely studied and ... -
Microwave Spectroscopic and Theoretical Investigations on Inter/Intra Molecular Bonding
(2018-05-09)The importance of weak interactions between molecules to life and all parts of science and engineering is unquestionable and there have been an enormous interest in such interactions. Among all the weak interactions, ... -
A New Class of Boron-Nitrogen Compounds : A Rational Approach for the Design and Development of Smart Materials
Replacing nonpolar homodiatomic C=C unit in a fully carbon -conjugated system with an isoelectronic polar heterodiatomic B-N fragment is an active area of research. The first BN/CC isosterism was demonstrated seven decades ... -
New Class of Tricoordinate Boron Based Donor-Acceptor (D-A) Systems Exhibiting External Stimuli Responsive Properties, Delayed Emission and Room Temperature Phosphorescence
The main thrust of this thesis is the design and development of a new class of boron-based acceptors, with a substituent which maintains good electronic coupling between boron and the other substitutes on boron, without ... -
Nonequilibrium Fluctuations, Quantum Optical Responses and Thermodynamics of Molecular Junctions
(2018-02-06)Mankind has come a long way since the invention of wheel to accessing information in the quintillionth of a second. At the heart of every invention ever made, there has been only one objective, to ease the way of living. ... -
Palladium and Nickel Chalcogenides as Electrocatalysts
(2017-12-02)In recent years, there has been an increasing interest on renewable energy sources as substitute to fossil fuels. Among various processes of energy generation, electrochemical methods such as storage and conversion systems, ... -
Platinum(II) Complexes as Dual Action DNA Crosslinking & Photochemotherapeutic Agents
(2017-12-07)The thesis work delineates the rational design and successful syntheses of platinum (II) complexes for achieving light promoted dual action anticancer properties. The research work focuses on the syntheses, elaborate ... -
Rational Design Facile Synthesis of Boryl Anilines : Intriguing Aggregation Induced Emission and External Stimuli Responsive Properties
(2018-07-26)The main thrust of this thesis is the development of facile synthetic routes for simple boryl anilines and study their structure-property correlations in both solid and solution states and to utilize this information to ... -
Self-Assembly and Cytotoxic Activity of Homometallic and Heterometallic Coordination Architectures
(2018-05-29)The alluring order in which complex biological networks exist in nature stimulated the interest of chemists to replicate such systems synthetically. With such examples as the deoxyribonucleic acid (DNA) double helix and ... -
Structure-Activity Correlation and Mechanistic Investigations of Glutathione Peroxidase-Like Catalytic Activity of Diaryl Diselenides
Hydroperoxides are very harmful and they can oxidize several biomolecules, causing different disease states. Glutathione peroxidase (GPx) is a mammalian selenoenzyme which protects human body from oxidative damage by ... -
Studies on BODIPY-conjugates of Copper and Zinc for Cellular Imaging and Photodynamic Therapy
Cancer is a dreadful disease that occurs due to the uncontrolled division of abnormal cells. Though there are different therapeutic modalities available for cancer, chemotherapy is considered as the most practiced method. ... -
Studies on Iron and Cobalt Complexes showing Photo-induced Anticancer Activity
In this thesis the various facets of the chemistry of photocytotoxic iron and cobalt complexes have been investigated along with their syntheses, characterization, evaluation of the photocytotoxic activities in various ... -
Studies on Oxovanadium(IV) Complexes for Photocytotoxicity and Cellular Imaging
The thesis work deals with different aspects of the chemistry of oxovanadium(IV) complexes, their interaction with DNA, photo-induced cleavage of double-stranded DNA, photocytotoxic effect on cancer and normal cells in ... -
Synthesis, Structural Elucidation and Anticancer Activity Studies on Metal Complexes of Nucleic Acid Constituents and their Derivatives
(2018-01-04)Metal-nucleic acid interaction studies have been gaining attention due to their biological and chemical importance. Nucleic acids are negatively charged bio-polymers and neutralization of their negative charge is essential ... -
Theoretical Investigation of H-Bonded O-H Vibrations, H-Atom Transfer and C-H Vibrations via Empirical Valence Bond and Local Mode Based Models
In this thesis, I have presented my work on properties of hydrogen(H) bonded systems, H-atom transfer reaction in solution and molecular vibrational spectra through theoretical inves-tigations. The studies are based on two ... -
Theoretical Studies of Energy Transport in Complex Systems
(2018-05-09)Photosynthesis involves the absorption of photons by light-harvesting pigments and the subsequent transfer of excitation from the absorption centre to the reaction centre. This highly efficient phenomenon of excitation ... -
Triarylborane Functionalized Dicyanovinyl and Acetylacetone Based Molecular Platforms : Building Blocks for Multiple Anion Sensors and Efficient Phosphorescence Emitters
(2018-02-20)Triarylborane Functionalized Dicyanovinyl and Acetylacetone Based Molecular Platforms: Building Blocks for Multiple Anion Sensors and Efficient Phosphorescence Emitters The main objective of this thesis is to design a ... -
Triarylborane-BODIPY Conjugates : White Light Emission, Multi-color Cell Imaging and Small Molecule Based Solar Cells
(2018-06-13)Luminescent boron containing materials find numerous applications in modern technologies such as display/lighting, bio-imaging and sensing. Thus, investigations of structure-property relationships in organic luminescent ... -
Ultrafast Raman Loss Spectroscopic Investigations of Excited State Structural Dynamics of Bis(phenylethynyl)benzene and trans-Stilbene
(2018-05-25)The subject of this thesis is the design and development of a unified set up for femtosecond transient absorption and ultrafast Raman loss spectroscopy and demonstrate its potential in capturing the ultrafast photophysical ... -
Understanding Ultrafast Molecular Structural Dynamics in Liquids : Ultrafast Raman Loss and Transient Absorption Study
The present thesis deals with the detailed ultrafast experimental studies on the ex-cited state vibrational dynamics of model chemical systems in condensed phase. The molecular systems are studied by means of Ultrafast ...