etd AT Indian Institute of Science: Recent submissions
Now showing items 141-160 of 8174
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Electrochemistry at complex interfacial geometries
A study of electrochemical response of interfaces, when one or more of the electrodes assume arbitrary or rough (random) geometries, is of utmost importance but is difficult to analyse. The importance arises from the fact ... -
Magnetism and exchange in the layered transition metal thiophosphates and their solid solutions
It was mentioned in the Introductory Chapter that changes in the magnetic behaviour of the intercalation compounds of the transition metal thiophosphates depend crucially on the magnetism of the host lattice. Hence an ... -
Copper (I) promoted allylic nucleophilic substitution: a synthetic and mechanistic study.
Abstract not available -
Electrode kinetics of hydrogen evoluion reaction & electrodeposition of silver, palladium & silver-palladium alloys.
It has been demonstrated that chemically modified manganese dioxide can be prepared by oxidation of appropriate mixed salt solutions by chlorate ion. Manganese dioxide–coated titanium electrode has been found to be ... -
Studies on the synthesis and oxidation of substituted hydrazines
The thesis pertains to investigations relating to the synthesis and oxidation of substituted hydrazines. The contents of this thesis can be categorised into two parts. The first part concerns the synthesis of hydrazines ... -
Application of electrochemical kinetics to predict the failure modes of nickle cadmium cells
A critical review of the literature on nondestructive techniques to predict failure modes of sealed rechargeable battery-cells, such as nickel-cadmium cells, has been made. It is thus concluded that a.c. impedance measurements ... -
Studies of hydrazinium salts
The present investigation aims at synthesis, characterization, reactivity, thermal properties and applications of some of the hydrazinium salts. In the introductory Chapter, a literature survey on the chemistry of hydrazine ... -
Studies on high energy hydrazine compounds
The present investigation aims at synthesis, characterisation, reactivity, thermal properties and applications of some of the high?energy materials of hydrazine. The chemistry of hydrazine is of interest because of its ... -
Aminolysis reactions of octachlorocycloterathophazene, Ph.D. Thesis
3–12. Conclusions – The present work embodies the first systematic investigations of the reactions of octachlorocyclotetraphosphazene with two primary aliphatic amines, viz., ethylamine and t-butylamine. In both cases, in ... -
Physical adsorption from mixtures of gases-Thesis submitted for the Degree of Doctor of Philosophy In the faculty of Science
The thesis deals with a study of the adsorption from binary mixtures of gases on solid surfaces. A major part of the investigations is carried out on silica gel, while a part of the work consists of an investigation on ... -
Electronic structure and spectroscopy properties of some thicarboy compounds
8.1 SEMI-EMPIRICAL PARAMETERS Different sets of bonding parameters in the CNDO/2 formalism and various approximations for evaluating the off-diagonal matrix element in the SCC-EH method were employed for a group of thioamides ... -
Combustion synthesis and properties of nanosize oxides : studies on solid oxide fuel cell materials
Salient Features The low?temperature initiated, self?propagating, and gas?producing combustion process, developed and used for the preparation of technologically important oxide materials, has now been successfully extended ... -
Coordination chemistry of lanthanides
Based on the studies on the lanthanide complexes of pyridine?1?oxide and its methyl?substituted derivatives, it has been concluded that the methyl substitution at the 4?position of the pyridine ring does not bring down the ... -
Reactivity of substituted thesis
The thesis embodies investigations carried out to understand the mechanism of thermal decomposition and explosion of some high?energy compounds of nitrogen. The importance of these compounds stems from the fact that the ... -
Thermal decomposition of zirconyl Oxalates of bivalent Metals
The introductory chapter begins with a brief account of the thermal decomposition of simple and complex oxalates. General theory of kinetics of decomposition of solids is also presented. The conventional ceramic method of ... -
Thermal decomposition of titanyl oxalates of bivalent metals
The present study reveals some interesting facts both on the thermoanalytical techniques in general and thermal decomposition of titanyl oxalates in particular. The results of thermal analyses and explanations based on ... -
Polarographic and potentiometric behaviour of amino acid complexes of uranyl and ferric ions
Abstract not available