| dc.contributor.advisor | Patel, C C | |
| dc.contributor.author | Balasubramanian, V | |
| dc.date.accessioned | 2025-11-19T09:08:43Z | |
| dc.date.available | 2025-11-19T09:08:43Z | |
| dc.date.submitted | 1980 | |
| dc.identifier.uri | https://etd.iisc.ac.in/handle/2005/7455 | |
| dc.description.abstract | Reactions of some Schiff-base complexes of diacetoxy boron with phenylisocyanate and nitrosating reagents have been investigated. Phenylisocyanation produces phenylamido-substituted derivatives by electrophilic attack by phenylisocyanate at γ-CH followed by prototropic rearrangement. Nitrosation takes place only in the case of diacetoxy acetylacetonephenylimino boron at γ-CH, producing isonitroso derivative, which gets coordinated to boron through oxygen of the isonitroso derivative, by dislodging the already coordinated carbonyl group of the Schiff-base. | |
| dc.language.iso | en_US | |
| dc.relation.ispartofseries | T01668 | |
| dc.rights | I grant Indian Institute of Science the right to archive and to make available my thesis or dissertation in whole or in part in all forms of media, now hereafter known. I retain all proprietary rights, such as patent rights. I also retain the right to use in future works (such as articles or books) all or part of this thesis or dissertation | |
| dc.subject | Schiff Base Complexes | |
| dc.subject | Phenylisocyanation Reactions | |
| dc.subject | Electrophilic Addition | |
| dc.title | The Reactions of Coordinated ligands - A
STU D Y O F THE REACTIVITY OF CO O R D IN ATED β-Diketones, β-Ketoimines, and Thio-β-Diketones | |
| dc.degree.name | PhD | |
| dc.degree.level | Doctoral | |
| dc.degree.grantor | Indian Institute of Science | |
| dc.degree.discipline | Science | |
