| dc.contributor.advisor | Samuelson, A G | |
| dc.contributor.author | Kathuria, Lakshay | |
| dc.date.accessioned | 2020-09-30T09:32:22Z | |
| dc.date.available | 2020-09-30T09:32:22Z | |
| dc.date.submitted | 2020 | |
| dc.identifier.uri | https://etd.iisc.ac.in/handle/2005/4596 | |
| dc.description.abstract | The thesis describes the study of arene-tethered and untethered Ru half-sandwich complexes as catalysts in the addition of hydroelements (E‒H, E = H, B, Si) across unsaturated C-C, C-N and C-O bonds and transfer hydrogenation which are two key reactions catalyzed by transition metal complexes. The transfer hydrogenation of ketones, hydrosilylation of imines, and hydroboration of vinyl arenes and aryl alkynes have been studied. Utilizing naturally occurring amino-acids, chiral (N-heterocyclic) NHC ligands and their Ir-NHC complexes were synthesized for asymmetric hydrosilylation of ketimines | en_US |
| dc.language.iso | en_US | en_US |
| dc.rights | I grant Indian Institute of Science the right to archive and to make available my thesis or dissertation in whole or in part in all forms of media, now hereafter known. I retain all proprietary rights, such as patent rights. I also retain the right to use in future works (such as articles or books) all or part
of this thesis or dissertation | en_US |
| dc.subject | Half-sandwich complexes | en_US |
| dc.subject | N-heterocyclic carbene | en_US |
| dc.subject | Transfer hydrogenation | en_US |
| dc.subject | hydrosilylation | en_US |
| dc.subject.classification | Research Subject Categories::NATURAL SCIENCES::Chemistry::Inorganic chemistry::Coordination chemistry | en_US |
| dc.title | Catalytic Studies with Ru and Ir Half-sandwich Complexes Bearing NHC Ligands | en_US |
| dc.type | Thesis | en_US |
| dc.degree.name | PhD | en_US |
| dc.degree.level | Doctoral | en_US |
| dc.degree.grantor | Indian Institute of Science | en_US |
| dc.degree.discipline | Faculty of Science | en_US |
