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Ruthenium Complexes Of Chiral And Achiral Phosphorus Ligands Based On The P-N-P Motif
(2007-09-05)
In recent years there is an increasing awareness of the importance of chiral phosphorus ligands in transition metal organometallic chemistry because of the utility of such complexes in homogeneous catalytic reactions. This ...
Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes
(Indian Institute of Science, 2007-06-22)
The bite angle of a diphosphine ligand plays an important role in determining the reactivity of a transition metal complex. The coordinated dihydrogen on a transition metal center can be activated toward homolysis or ...