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Mechanistic Studies of Transfer Hydrogenation Catalyzed by Ru(ll)-Half-Sandwich and Group 6 NHC complexes
The thesis explores the mechanistic aspects of transfer hydrogenation of ketones and hydrosilylation of imines; two commonly used organic transformations catalyzed by ruthenium half-sandwich complexes of 2-oxazolidinethiones, ...
Protein Adsorption on Gold Nanoparticle and Protein Surfaces Probed by Second Harmonic Light Scattering
Second harmonic light scattering (SHLS) is a highly sensitive technique to probe
reactions at interfaces/surfaces because of symmetry breaking at the interface/surface
produces a large surface polarization which gives ...
Design and Development of Proteasome Activity Modulators: A Novel Strategy for the Treatment of Diabetes Mellitus
Design and Development of Proteasome Activity Modulators: A Novel Strategy for the Treatment of Diabetes Mellitus
Abstract
The ubiquitin-proteasome system (UPS) is the major pathway for degradation of the intracellular ...
Zeolitic Imidazolate Framework (ZIF-8) Supported Nanoparticles: Synthesis and Applications
Nanoparticles have gained great interest in various fundamental and applied areas of science and technology due to their tunable size dependent properties which is not achievable by their bulk counterparts. Nanoparticles ...
Sol-gel based organic-inorganic hybrid coatings for corrosion protection of aerospace aluminium alloy
Aluminium metal is known for its high electrical conductivity, thermal conductivity and high reflectivity. Aluminium alloys of 2XXX series, particularly the 2024 alloy with the quaternary Al–Cu–Mg–Mn composition are widely ...
Structural and Solvent Effects on Excited State Dynamics of Rhenium(I) Tricarbonyl α-Diimine Complexes: A Time-Resolved Spectroscopic and Computational Study
The nature of the lowest excited state in rhenium(I) complex with 1,10-phenathroline as ligand was first reported by Mark Wrighton and David. L. Morse. Since then many rhenium(I) complexes with different ligands having ...
Non-covalent interactions in Crystals and Heterocycles of Sulphur and Selenium
Hydrogen bonding plays a very important role in the fields of both chemistry and biology. Conventionally it is represented as D-H---A, where D is the donor atom, A is the acceptor atom and H is the hydrogen atom. It has ...
Design, Synthesis and Optical Characterization of 1,8-Naphthalimide based D-pi-A System
Design, Synthesis and Optical Characterization of 1,8-Naphthalimide based D-pi-A System
Luminescent materials find a lot of application in the field of OLEDs and bio-medical applications [1-2]. Our group has recently ...
Computational Study of General Relationships in Chemistry: C−C, C−N, and B−B Coupling, B−B Catenation, and 2D Metal Borides
Elements in the periodic table are categorized into four major blocks, main group (MG) elements, transition metals (TM), lanthanides (Ln), and actinides (An), which differ dramatically. Recent studies revealed some interesting ...
Ethylene Glycol in the Liquid State: Structure, Conformation and Dynamics - A Study Using Ab Initio Molecular Dynamics Simulations
Ethylene glycol (EG) is an important organic molecule with unique properties and a wide range of applications. The EG molecule shares a structural motif with many biomolecules and serves as a part of the training set for ...