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Self-Assembly Of Functional Supramolecular Architectures via Metal-Ligand Coordination
(2015-09-09)
Over the past few decades, supramolecular self-assembly has become an alternative synthetic tool for constructing targeted discrete molecular architectures. Among various interactions, metal-ligand coordination has attracted ...
Functionalized Hyperbranched Polymers And Nonionenes
(2016-10-20)
In 1980’s a new class of material named as dendrimer became popular both in the field of polymer science and engineering. Dendrimer is an example of symmetric, highly branched three dimensional globular nano-object. It ...
Synthesis, Physiochemical And Electrochemical Studies On Iridium, Osmium And Graphene Oxide-Based Nanostructures
(2017-05-25)
Nanoscience dominates almost all areas of science and technology in the 21st century. Nanoparticles are of fundamental interest since they possess unique size dependent properties (optical, electrical, mechanical, chemical, ...
Electronic Structure And Bonding In Metallaboranes And Main Group Compounds
(2016-05-04)
This thesis entitled “Electronic Structure and Bonding in Metallaboranes and Main Group Compounds” consists of five chapters. Chapter 1 gives an exposition of concepts and techniques used in understanding the electronic ...
Dynamics Of Activated Processes Involving Chain Molecules
(2009-09-11)
This thesis presents our recent study of few interesting problems involving activated processes. This chapter gives an overview of the thesis.
It is now possible to do single molecule experiments involving enzyme molecules. ...
Studies On The Photocytotoxic Effect Of Ferrocene-Conjugated Copper(II) Complexes
(2016-04-29)
The present thesis deals with different aspects of the chemistry and photo-biology of various ferrocene-conjugated metal complexes, their interaction with double helical DNA, DNA photocleavage and photo-enhanced cytotoxicity ...
An Architectural Exploration in Coordination Driven Self-Assembly & Fluorescent Imidazolium Salts as Picric Acid Receptors
(2017-10-11)
Nature has always remained a constant source of inspiration for chemists for synthesizing natural products, mimicking enzymatic reactions or to construct molecular architectures resembling biological assemblies. With the ...
Serendipitous Assembly Of 3d Metal-Ion Polyclusters : Structures, Magnetic Behavior And Theoretical Studies
(2017-02-22)
The last two decades have seen extensive growth in interest in metal-ion assemblies, especially for building new polynuclear exchange-coupled magnetic systems. However, the concept of designing polynuclear extended structures ...
Mechanistic Insights Into Small Molecule (Amine-Boranes, Hydrogen, Methane, Formic Acid Carbon dioxide) Activation Using Electrophilic Ru(II)-Complexes
(2017-11-09)
Current fossil fuels (Coal and Petroleum) based economy is not sustainable in the long run because of its dwindling resources, and increasing concerns of climate change due to excessive carbon dioxide (CO2) emission. To ...
Mapping The Reaction Coordinate For The Oxidative Addition Of Molecular Hydrogen To A Metal Center
(2010-07-15)
The binding of molecular hydrogen to a metal center leads to the elongation of the H−H bond and subsequently to its cleavage along the reaction coordinate for the oxidative addition of H2. There has been considerable ...