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Now showing items 11-18 of 18
Serendipitous Assembly Of 3d Metal-Ion Polyclusters : Structures, Magnetic Behavior And Theoretical Studies
(2017-02-22)
The last two decades have seen extensive growth in interest in metal-ion assemblies, especially for building new polynuclear exchange-coupled magnetic systems. However, the concept of designing polynuclear extended structures ...
Mechanistic Insights Into Small Molecule (Amine-Boranes, Hydrogen, Methane, Formic Acid Carbon dioxide) Activation Using Electrophilic Ru(II)-Complexes
(2017-11-09)
Current fossil fuels (Coal and Petroleum) based economy is not sustainable in the long run because of its dwindling resources, and increasing concerns of climate change due to excessive carbon dioxide (CO2) emission. To ...
Biomimetic Studies on Tyrosine- and Phenolate- Based Ligands and their Metal Complexes
(2017-11-14)
Tyrosine (4-hydroxyphenylalanine) is one of the naturally occurring 22 amino acids. The importance of tyrosine is due to the presence of its phenolic side chain. In biological systems, the tyrosyl residue in proteins is ...
Synthesis of Metal and Metal Oxide Nanosponges for Hydrogen Storage and Catalytic Applications
(2017-11-28)
Nanoporous metal represents a particular form of a metal, which combines the characteristics of metals, such as good thermal and electrical conductivity, catalytic activity with the materials properties characteristic of ...
Influence of Ancillary Ligands in the Chemistry of Transition Metal σ-Complexes
(2017-09-27)
This thesis work is based on an investigation of intermediates involved in various metal mediated catalytic reactions such as hydrogenation, hydroboration, functionalization of methane etc. An intermediate dictates the ...
Organic Imine Cages : Self-Sorting and Application
(2017-11-14)
Biological systems have the incredible ability to accomplish uncommon chemical transformations with supreme delicacy. Many of those chemical transformations take place within the pocket of enzymes, which provide unique ...
A Computational Study of C-H Binding, C-H Activation and Fluxional Processes of d6 Half- Sandwich Complexes
(2017-11-24)
Significant developments have been made in the field of C–H activation. However, various disadvantages, mainly low reactivity and selectivity, limit their usage in large-scale synthesis. It is crucial to understand the ...
Platinum(II) Complexes as Dual Action DNA Crosslinking & Photochemotherapeutic Agents
(2017-12-07)
The thesis work delineates the rational design and successful syntheses of platinum (II) complexes for achieving light promoted dual action anticancer properties. The research work focuses on the syntheses, elaborate ...