Browsing Inorganic and Physical Chemistry (IPC) by Subject "Dihydrogen Complexes"
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Chemistry of Ru(II) Complexes Bearing N-heterocyclic Carbene, Hydride, and Dihydrogen Ligands : Synthesis, Mechanistic Insights, and Applications
Introduction N-heterocyclic carbenes (NHC) are strong donors and weak acceptors. Also, NHC forms strong metal-carbon bonds in metal complexes and hence complexes bearing NHC ligands are in general, thermally stable. ... -
Heterolytic activation of molecular hydrogen by transition metal complexes
New iron hydride complexes of the type trans-[(dppe)?Fe(H)(RCN)][BF?] (RCN = nitrile) with varying degree of ?-accepting ability of the nitrile moiety have been prepared and characterized. The protonation reactions of these ... -
Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes
(Indian Institute of Science, 2007-06-22)The bite angle of a diphosphine ligand plays an important role in determining the reactivity of a transition metal complex. The coordinated dihydrogen on a transition metal center can be activated toward homolysis or ... -
Utilization Of Small Molelcules In C1 Chemistry
(2011-10-25)