Browsing Inorganic and Physical Chemistry (IPC) by Title
Now showing items 100-119 of 279
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Intercalation Of Alkyl Surfactants In Layered Double Hydroxides : The Anchored Bilayer In Dispersions And The Condensed Phase
(2013-05-23)Bilayers formed by molecules that possess long alkyl hydrophobic tails are ubiquitous in the natural world manifesting both in biological systems as well as in chemistry. The lipid bilayer is an integral feature of cell ... -
Interfacial Studies Using Organized Organic and Inorganic Films
Interfaces play an important role in various fields, such as catalysis, charge transfer / electrochemical processes, chemical reactions, molecular electronics, wetting, and biology. Building functional structures with a ... -
Investigation of Psychrophilic SUMO Proteases: Towards a More Efficient SUMO Protease at Lower Temperature
Covalent attachment of the fusion protein, Small Ubiquitin-like modifier (SUMO), to recalcitrant target proteins (especially transmembrane proteins) make purification of the target protein much easier by enhancing its ... -
Investigations of Structure-Property Relationships in NPI and BODIPY Based Luminescent Material
(2018-08-09)Luminescent materials find numerous applications in recent times and have enriched human lives in several different ways. From display and lighting technologies to security, sensing and biological investigations, luminescent ... -
Investigations on Azide Functional Polymers as Binders for Solid Propellants
(2018-05-09)This thesis contains investigations in the area of polymers herein propellants binders are modified functionally to meet the requirements of future energetic propellants. Chapter 1 contains a broad introduction to the area ... -
Investigations on the Pi Distortivity Problem and On the Use of Single Atom Thick Layers as Filters
It has traditionally been believed that pi-electrons stabilize the D6h structure of benzene. However, this was questioned both using theoretical arguments, as well as circumstantial, experimental evidence. The theoretical ... -
Isoform Specific Synthetic Glutathione Peroxidase Mimetics in Redox Regulation of Cell Death and Diseases
Reactive oxygen species (ROS)-induced oxidative stress has been implicated in various pathologies and cell death processes. Cells have antioxidant systems to neutralize the harmful effects of excess ROS. Glutathione ... -
Itaconate Based Novel Amphiphilic Polymer Architectures
Amphiphiles are natural or synthetic molecules consisting of hydrophilic polar head group and hydrophobic non-polar hydrocarbon tail. Beyond a certain concentration, known as critical micellar concentration (CMC), amphiphilic ... -
Itaconate-based Periodically Grafted Polyesters
(2017-12-03)Block copolymers can self-assemble into a variety of periodic nanostructures and therefore, are promising candidates for a diverse range of applications. While self-assembly of block copolymers has been widely studied and ... -
Mapping The Reaction Coordinate For The Oxidative Addition Of Molecular Hydrogen To A Metal Center
(2010-07-15)The binding of molecular hydrogen to a metal center leads to the elongation of the H−H bond and subsequently to its cleavage along the reaction coordinate for the oxidative addition of H2. There has been considerable ... -
Materials For Hydrogen Generation, Storage, And Catalysis
(2013-01-22)Hydrogen, nature’s simple and the most abundant element has been in the limelight for the past few decades from the stand point of the so-called hydrogen economy. With a high calorific value (142 MJ/kg) that is three times ... -
Mechanistic Insights Into Small Molecule (Amine-Boranes, Hydrogen, Methane, Formic Acid Carbon dioxide) Activation Using Electrophilic Ru(II)-Complexes
(2017-11-09)Current fossil fuels (Coal and Petroleum) based economy is not sustainable in the long run because of its dwindling resources, and increasing concerns of climate change due to excessive carbon dioxide (CO2) emission. To ... -
Mechanistic Investigation of Metal Promoted Nucleophilic Additions
(2017-11-30)Nucleophilic additions are an important class of reactions in the preparation of several organic compounds. Metals facilitate nucleophilic additions in many cases. The present work Mechanistic Investigation of Metal Promoted ... -
Mechanistic Studies of Transfer Hydrogenation Catalyzed by Ru(ll)-Half-Sandwich and Group 6 NHC complexes
The thesis explores the mechanistic aspects of transfer hydrogenation of ketones and hydrosilylation of imines; two commonly used organic transformations catalyzed by ruthenium half-sandwich complexes of 2-oxazolidinethiones, ... -
Metallo-β-Lactamase, Phosphotriesterase And Their Functional Mimics
(2011-01-11)Metallohydrolases with dinuclear-zinc active sites perform many important biological hydrolytic reactions on a variety of substrates. In this regard, metallo-β-lactamases (mβ1, class B) represent a unique subset of zine ... -
Micro-spectroscopic studies on Mycobacteria & Cancer cells
Evasion of the immune system is a key hallmark of cancer progression. Developing strategies that diagnose early the immune-cancer synapse may lead to long term cures from these aggressive cancers. We aimed to develop optical ... -
Microwave Rotation-Tunnelling Spectroscopic and Theoretical Studies on Weakly Bound Molecular Complexes: Intermolecular Bonding across the Periodic Table
Intermolecular interactions appear to be well understood in a broad sense today; at a deeper molecular level, it is still evolving. Spectroscopy in this isolated state proved to be a first step toward understanding the ...