Browsing Inorganic and Physical Chemistry (IPC) by Title
Now showing items 48-67 of 539
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Chemistry of hydrazine derivatives
The chemistry of hydrazine and its derivatives is of interest because of their use as rocket fuel, solid propellant oxidizers, explosives, antioxidants, insecticides, food preservatives, pharmaceuticals and materials for ... -
Chemistry of Ru(II) Complexes Bearing N-heterocyclic Carbene, Hydride, and Dihydrogen Ligands : Synthesis, Mechanistic Insights, and Applications
Introduction N-heterocyclic carbenes (NHC) are strong donors and weak acceptors. Also, NHC forms strong metal-carbon bonds in metal complexes and hence complexes bearing NHC ligands are in general, thermally stable. ... -
Chemistry of Ru(II) Complexes Bearing Sigma Bonded H-X (X = H, Si, C) Species/Fragments
(2018-04-11)Introduction The chemistry of transitional metal complexes bearing σ-bonded H−X (X = H, Si, C) species/fragments, the so called σ-complexes, are key intermediates in catalytic processes such as hydrogenation, hydrosilylation, ... -
Chiral Bisphosphinites For Asymmetric Catalysis
(2010-07-21)Chiral bisphosphinites are well-documented alternatives for chiral bisphosphines as ligands that can be exploited in various asymmpetric syntheses. Particularly, vicinal biarylphophinite ligands give a seven membered chelate ... -
Cobalt-nhc Complexes and Diazabutadienes in Activation of Mono/Diboron Compounds and Their Application in C-b Coupling Reactions
Boronic acid(esters) have been well recognized as an indispensable coupling partner in the Suzuki-Miyaura cross coupling reactions producing a vast spectrum of molecules, applicable in the diverse field ranging from medicinal ... -
Combusition of polymers and the effect of fore retardant additives : a mechanistic approach.
CHAPTER 1 This chapter constitutes a general description of the combustion of polymers and the various processes involved. Processes like gas‑phase reactions, surface reactions and solid‑phase reactions are discussed in ... -
Combustion synthesis and properties of ferroelectrics, relaxor ferroelectrics & microwave resonator materials
Dielectric materials include ferroelectrics, relaxor ferroelectrics and microwave resonators which are classified on the basis of their dielectric performances like dielectric constant, dielectric loss and piezoelectric ... -
Combustion synthesis and properties of fine particle oxide materials: studies on Ferrites
Synthesis of oxide materials with desired structure and properties is of prime importance in Solid State Chemistry and Materials Science. Since the discovery of superconductivity in oxide ceramics, there has been renewed ... -
Combustion synthesis and properties of fine particles spinel, Perovskite and K2NiF4 Type oxides
Technologically important fine?particle, mixed?metal, transition?metal oxides such as spinels (MCr?O?), perovskites (LnCrO?, La(Sr)MnO?, LaCoO? and LaNiO?) and K?NiF??type oxides (La?CoO?, La?NiO?, La?CuO? and La?.?Sr?.?CuO?) ... -
Combustion synthesis and properties of nanosize oxides : studies on solid oxide fuel cell materials
Salient Features The low?temperature initiated, self?propagating, and gas?producing combustion process, developed and used for the preparation of technologically important oxide materials, has now been successfully extended ... -
Complex plane and D.C. polarographic behaviour of zinc and cadmium in ethanolemine
Abstract not available -
Complex plane and DC polarographic studies of lead (11) ethanolamine (mono-D1 and TR1-) systems
A detailed investigation on the polarographic (d.c. and complex plane) behavior of lead ion in sodium perchlorate, potassium nitrate, potassium chloride, ethanolammonium (mono-, di-, and tri-) perchlorates and the respective ... -
Computational Studies of Heavier Main Group Elements: Control of Lewis Acidity of Bi and Sb by Charge and Ligand Design, and Structural Variations of [Fe(CO)4]2E2 and E2CH2 Isomers (E = C–Pb)
Traditional main group compounds demonstrate Lewis acidity due to the presence of vacant p- orbitals. Hydrides of lighter main group elements, such as NH3, function as Lewis bases. However, introducing highly electronegative ... -
Computational Studies of the Electronic Structures and Ring Contraction Reactions of Pn (n=4-6) Ring in Double and Triple Decker Complexes, and an Orbital Engineering Approach to Stabilise Borozene (B6H6)
The well established chemistry of ferrocene1-3 and different sandwich scaffolds4,5 with organic rings prompted us to explore the electronic structures and reactivity of sandwich complexes involving inorganic rings, i.e., ... -
Computational Studies on Interstellar Molecular Species : From Formation to Detection
(2018-03-01)Initiated with the purpose of assigning the Fraunhofer lines in the solar spectrum to atomic transitions in the 18th century, the collaboration between spectroscopists and astrophysicists has remained fruitful, successful ... -
Computational Studies On Macropolyhedral Boranes And Metallaboranes
(2011-01-11)The analysis of nature of bonding in non-classical structures is always an intriguing area of research. Typical examples of such systems are polyhedral boranes that exhibit fascinating cluster bonding where the traditional ... -
A Computational Study of C-H Binding, C-H Activation and Fluxional Processes of d6 Half- Sandwich Complexes
(2017-11-24)Significant developments have been made in the field of C–H activation. However, various disadvantages, mainly low reactivity and selectivity, limit their usage in large-scale synthesis. It is crucial to understand the ... -
Computational Study of General Relationships in Chemistry: C−C, C−N, and B−B Coupling, B−B Catenation, and 2D Metal Borides
Elements in the periodic table are categorized into four major blocks, main group (MG) elements, transition metals (TM), lanthanides (Ln), and actinides (An), which differ dramatically. Recent studies revealed some interesting ... -
A Computational Study Of Nucleophilic Attacks In Organometallic Complexes
(2012-04-23)A wide variety of computational methods are available for exploring molecular structures and reactivity in chemistry. These range from molecular mechanics calculations allowing determination of the geometry of a molecule ...