Browsing Inorganic and Physical Chemistry (IPC) by Title
Now showing items 149-168 of 279
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Platinum(II) Complexes as Dual Action DNA Crosslinking & Photochemotherapeutic Agents
(2017-12-07)The thesis work delineates the rational design and successful syntheses of platinum (II) complexes for achieving light promoted dual action anticancer properties. The research work focuses on the syntheses, elaborate ... -
Platinum(II)-BODIPY Conjugates for Organelle Targeted Photodynamic Therapy in Red Light
The serendipitous discovery of Cisplatin (CP, Peyrone's chloride) as an anticancer agent in 1965 by Barnett Rosenberg led to the evolution of other platinum-based anticancer drugs, namely, Carboplatin in 1989 and Oxaliplatin ... -
Polymerizable Porogen – Direct generation of internally functionalized porous polymers
Bicontinuous functional porous polymers are desirable in terms of pore accessibility, particularly for applications in templating, chromatographic separation, and catalysis. Bicontinuous morphologies can be obtained by ... -
Polynuclear Coordination Assemblies : Synthesis, Crystal Structures And Magnetic Behavior
(2013-05-23)Construction of polynuclear metal assemblies from discrete 0D clusters to extend 3D networks, comprised of metal ions and bridging organic/inorganic ligands has attracted immense attention, owing to their intriguing network ... -
Probing The Equilibrium Geometry Of Weakly Interacting Systems In Solution By Hyper-Rayleigh Scattering
(2014-08-11)Under the electric dipole approximation, second harmonic of the incident light is scattered by a collection of randomly oriented molecular dipoles in solution due to instantaneous orientational fluctuation which is ... -
Probing The Origin Of Second Harmonic Generation From Copper Nanoparticles In Solution By Hyper-Rayleigh Scattering
(2010-08-09)In recent years, coinage metal nanoparticles have emerged as materials with largest quadratic optical nonlinearity. Their first hyperpolarizabilities (β) are very high (105-106 x 10-30 esu) but such large values were quite ... -
Protein Adsorption on Gold Nanoparticle and Protein Surfaces Probed by Second Harmonic Light Scattering
Second harmonic light scattering (SHLS) is a highly sensitive technique to probe reactions at interfaces/surfaces because of symmetry breaking at the interface/surface produces a large surface polarization which gives ... -
Quadratic Nonlinearity In Covalently And Non-Covalently Linked Molecules In Solution
(2008-10-01)This thesis deals with the investigation of the first hyperpolarizabilities (β) of a large number of molecules linked to other molecules either covalently or noncovalently. Chapter 1 gives a brief introduction to ... -
Quadratic Optical Nonlinearity And Geometry Of 1:1 Electron Donor Acceptor Complexes In Solution
(2010-06-04)The knowledge of geometry of molecular complexes formed via molecular association in solution through weak interactions is always important to understand the origin of stability and function of an array of molecules, ... -
Raman and IR Spectroscopic Studies of Bacteria, Endotoxin, DNA and Lipoproteins
In the past few decades, vibrational spectroscopy has emerged as a powerful technique in biomedical research. Raman and IR spectroscopy, which are based on signatures specific to molecular vibrations, has found a wide ... -
Raman Spectroscopy Applications to High Energy Materials
(2018-01-28)Detection of explosives has always been a challenging issue all over the world. Different analytical techniques and instrumentation methods have been explored to obtain a 100% fail proof detector. Some technologies have ... -
Rational Design Facile Synthesis of Boryl Anilines : Intriguing Aggregation Induced Emission and External Stimuli Responsive Properties
(2018-07-26)The main thrust of this thesis is the development of facile synthetic routes for simple boryl anilines and study their structure-property correlations in both solid and solution states and to utilize this information to ... -
Rational Synthesis, Stabilization, and Functional Properties of Metal and Intermetallic Nanoparticles
(2018-04-11)The confluence of intriguing size and morphology dependent optical and chemical properties with versatile application in various fields, such as energetic and magnetic makes monometallic nonmaterial of high fundamental ... -
Reductive And Metathetic Coupling Reactions Mediated By Group (IV) Metal Alkoxides
(2010-10-19)Several organic transformations are mediated by group(IV) metal alkoxides. The reactivity is based on the basic nature of alkoxide group, Lewis acidic nature of the group(IV) metals, insertion of unsaturated molecules into ... -
Resonance Energy Transfer Using ZnO Nanocrystals And Magnetism In The Mixed Metal Layered Thiophosphates, Mn1-xFexPS3(0≤x≥1)
(2013-07-26)This thesis consists of two parts. The first part deals with the visible emission of ZnO Nanocrystals and its possible application in Resonance Energy Transfer (RET) studies. The second part of the thesis is on the magnetic ... -
Reversible Redox Switching of First Hyperpolarizability (Β) of Metallorganic Complexes
The concept of molecular switches has garnered enormous interest because of the vital role of these switches as components in molecular electronic/photonic devices, signal transmission and optical communication. Compounds ... -
Room Temperature Molten Liquids Based On Amides : Electrolytes For Rechargeable Batteries, Capacitors And Medium For Nanostructures
(2011-01-10)Room temperature molten liquids are proposed to be good alternates for volatile and harmful organic compounds. They are useful in varied areas of applications ranging from synthesis, catalysis to energy storage molten ... -
Room Temperature Phosphorescence and Circularly Polarized Luminescence Characteristics of Phosphine Oxides and Phosphoramides
Room temperature phosphorescence (RTP) materials have attracted much attention in recent years owing to their potential applications in organic light-emitting diodes (OLEDs), security writing, time-gated bio-imaging, ... -
Rotational Specroscopic And Theoretical Investigations Of Non-conventional Hydrogen Bonds
(2014-11-12)The nature of interactions within a molecule, i.e. chemical bonding, is well understood today. However, our understanding about intermolecular interactions, which has great relevance in nature, is still evolving. Historically ...