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Radical and Lewis Acid Mediated Syntheses of Panaginsene, Indole-Fused Azabicyclo[3.3.1]Nonane and Davanoids
The thesis contains radical and Lewis acid-mediated syntheses of panaginsene, indole-fused
azabicyclo[3.3.1]nonanes, and davanoids. The thesis includes three chapters; chapter-I
contains the total synthesis of panaginsene, ...
Diverse Applications of Luminescent Metallocholate Hydrogels
Supramolecular gels are soft materials consisting of a solid three-dimensional network with noncovalent interactions such as hydrophobic interactions, hydrogen bonding, cation-п, and п- п interactions. Due to their soft, ...
Dynamics of Quantum Supercooled Liquids: A Mode Coupling Approach
In this thesis, I use the quantum mode coupling theory (QMCT) formulation to
study the dynamics in a supercooled liquid to understand how quantum fluctuations affect the liquid-glass transition. I calculate the Kubo-transformed ...
Studies on BODIPY Appended Ruthenium(II) Complexes for Bioimaging and Photodynamic Therapy Applications
Photodynamic therapy (PDT) is a medical technique that utilizes light, oxygen, and a photosensitizer to treat several medical conditions, including cancer. Because of the limitations and side effects of traditional anticancer ...
Towards Electronic Scale Dynamics of Chemical Bonding in Isolated Molecules and Solvated Species
The chemical bonding in molecules and molecular clusters is determined by the nature of the electron density distribution between the atoms. Over the past century, different theories such as Lewis’s bond, valence-bond ...
Total Synthesis of Piperidine and Pyrrolidine Alkaloids and Towards the Total Synthesis of Strychnine
Total synthesis of natural products is an important area of contemporary interest in synthetic
organic chemistry. Total synthesis of natural products serves as a platform for the development of
new synthetic strategies ...
Ion insertion and Ion-host Interactions in Diketopyrrolopyrrole-based π-Conjugated Polymers
π-conjugated organic semiconductors are a class of technologically important materials with broad applicability in areas as diverse as energy conversion and storage, bioelectronics, and consumer electronics. This is because ...
A Study of Synthesis and Optoelectronics of Copper Iron Chalcogenide Nanocrystals
Copper iron chalcogenides constitute a promising class of optoelectronic materials courtesy of their narrow bandgaps and earth abundant constitution. However, they are yet to receive the attention they deserve due to the ...
Structural and Solvent Effects on Excited State Dynamics of Rhenium(I) Tricarbonyl α-Diimine Complexes: A Time-Resolved Spectroscopic and Computational Study
The nature of the lowest excited state in rhenium(I) complex with 1,10-phenathroline as ligand was first reported by Mark Wrighton and David. L. Morse. Since then many rhenium(I) complexes with different ligands having ...
Low Power Resistive Photon- and Gas- Sensors
Sensors, be it for temperature, pressure, acoustic, light or gas to name a few have become an indispensable part of human life. Light sensors or photodetectors have widespread usage in modern portable electronics as camera ...