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Rotational Spectroscopic And Ab Initio Studies On The Weakly Bound Complexes Containing 0-H...π And S-H...π Interactions
(2010-11-22)
Work reported in this thesis mainly comprises of the assignments and analysis of the rotational spectra and structures of three weakly bound complexes: C2H4•••H2S, C6H5CCH•••H2O and C6H5CCH•••H2S. All the data have been ...
Aspects Of The Chemistry Of Iron Complexes Showing DNA Photo-cleavage Activity
(2010-12-30)
The present thesis deals with different aspects of the chemistry of iron complexes, their interaction with DNA and photo-induced cleavage of double-stranded DNA.
Chapter I presents a general introduction on metal-based ...
Antioxidant Activity Of The Anti-Inflammatory Compound Ebselen And Its Analogues : Role Of Nonbonded Interactions
(2010-10-05)
Although considered as a poison for long time, the importance of selenium as an essential trace element is now well recognized. In proteins, the redox active selenium moiety is incorportated as selenocysteine (Sec), the ...
Electrochemical Studies Of PEDOT : Microscopy, Electrooxidation Of Small Organic Molecules And Phenol, And Supercapacitor Studies
(2011-01-25)
Following the discovery of electronic conductivity in doped polyacetylene, various studies on conducting polymers have been investigated. These polymers are essentially characterized by the presence of conjugated bonding ...
Computational Studies On Macropolyhedral Boranes And Metallaboranes
(2011-01-11)
The analysis of nature of bonding in non-classical structures is always an intriguing area of research. Typical examples of such systems are polyhedral boranes that exhibit fascinating cluster bonding where the traditional ...
Targeted Delivery of Cytotoxic Metal Complexes into Cancer Cells with and without Macromolecular Vehicles
(2018-04-12)
Anticancer active metal complexes such as cisplatin are routinely used for treating various cancers since 1978. However, the side effects of cisplatin overwhelm its therapeutic potential, especially in the latter stages ...
Vibrational Microspectroscopic Studies of Biomedical Conditions Using Model Systems
(2018-05-08)
Over the last century, despite enormous advancements in biomedical research and the development of sophisticated analytical instruments many diseases continue to be a burden on humankind particularly on the aged. This is ...
Physicochemical, Electrical and Electrochemical Studies on Titanium Carbide-Based Nanostructures
(2018-04-03)
Materials for studies related to nanoscience and nanotechnology have gained tremendous attention owing to their unique physical, chemical and electronic properties. Among various anisotropic nanostructures, one dimensional ...
Syntheses and Structure Elucidations of Ternary Metal (Cu/Co)Complexes with Nucleic Acid Constituents
(2018-05-07)
The thesis is divided into four chapters
Chapter 1 provides a brief introduction to the metal-nucleic acid interactions, the role of synthetic models to understand them with both solution (potentiometric) and solid state ...