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Investigations on the Pi Distortivity Problem and On the Use of Single Atom Thick Layers as Filters
It has traditionally been believed that pi-electrons stabilize the D6h structure of benzene. However, this was questioned both using theoretical arguments, as well as circumstantial, experimental evidence. The theoretical ...
Protein-Nanomaterial Interactions: Structural And Dynamic Aspects
Owing to their unique properties, the noble metallic nanoparticles and graphenic nanomaterials find their applications in diverse fields of science. Particularly in the field of biomedicine, nanomaterials are being used ...
Electrochemical Conversion of Methyl Ketones to Esters
The need for sustainable and efficient organic synthesis has inspired chemists to embrace classic technologies like electrochemistry and photochemistry. In addition to being an environmentally benign method to synthesize ...
Catalytic Studies with Ru and Ir Half-sandwich Complexes Bearing NHC Ligands
The thesis describes the study of arene-tethered and untethered Ru half-sandwich complexes as catalysts in the addition of hydroelements (E‒H, E = H, B, Si) across unsaturated C-C, C-N and C-O bonds and transfer hydrogenation ...
Syntheses and Structure Elucidations of Co-crystal with Nicotinamide Co-former
Abstract :
Co-crystals consist of two or more components that form a unique crystalline structure having unique properties. The components interact via non-covalent, ionic interaction, van der Waals interactions and π-π ...
Studies on Layered Ternary Metal Chalcogenides: Electronic devices, Sensors and Electrocatalysis
Atomically thin two-dimensional (2D) materials have gained tremendous interest since the discovery of graphene in 2004 due to their unique physical and chemical properties. They have been used in various research fields ...
Micro-spectroscopic studies on Mycobacteria & Cancer cells
Evasion of the immune system is a key hallmark of cancer progression. Developing strategies that diagnose early the immune-cancer synapse may lead to long term cures from these aggressive cancers. We aimed to develop optical ...
Design and Application of Self-Assembled Coordination Cages for Catalysis and as Drug Carrier
In summary the present thesis accounts for the design and synthesis of various coordination cages
formed through the self-assembly reaction of the newly designed pyridine and pyrimidine based
ligands with various 90° ...
Aqueous and Non- aqueous dispersions of MoS2 Nanosheets
The focus of this thesis is an attempt
to provide a molecular perspective of the interactions of solvent and ligand molecules with
sonication assisted exfoliated MoS2 nanosheets in aqueous and non-aqueous dispersions.
In ...
Chemistry of carbonized metallic nanomaterials
Magnetic nanomaterials have received significant attention because of their remarkable
properties enabling applications in various fields such as catalysis, as contrast agents for
magnetic resonance imaging, in sensing ...