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Hydrophobicity and Composition-Dependent Anomalies in Aqueous Binary Mixtures, along with some Contribution to Diffusion on Rugged Energy Landscape
(2018-01-28)
I started writing this thesis not only to obtain a doctoral degree, but also to compile in a particular way all the work that I have done during this time. The articles published during these years can only give a short ...
Synthesis, Structure and Catalytic Properties of Pd2+, Pt2+ and Pt4+ Ion Substituted TiO2
(2018-04-05)
After introducing fundamentals of catalysis with noble metal surfaces especially Pt metal for CO oxidation and subsequent developments on nano-crystalline Pt metals supported on oxide supports, an idea of Pt ion in reducible ...
Chiral Bisphosphinites For Asymmetric Catalysis
(2010-07-21)
Chiral bisphosphinites are well-documented alternatives for chiral bisphosphines as ligands that can be exploited in various asymmpetric syntheses. Particularly, vicinal biarylphophinite ligands give a seven membered chelate ...
A Study on Digestive Ripening Mediated Size and Structure Control in Nanoparticles Prepared by Solvated Metal Atom Dispersion Method
(2017-12-16)
Recent advancements in nanotechnology and emerging applications of nanomaterials in various fields have stimulated interest in fundamental scientific research dealing with the size and structure controlled synthesis of ...
Mapping The Reaction Coordinate For The Oxidative Addition Of Molecular Hydrogen To A Metal Center
(2010-07-15)
The binding of molecular hydrogen to a metal center leads to the elongation of the H−H bond and subsequently to its cleavage along the reaction coordinate for the oxidative addition of H2. There has been considerable ...
Understanding Solvent Effect On Triplet State Structure Of Thioxanthone And Its Derivatives Using Time-Resolved Resonance Raman Spectroscopy
(2014-05-01)
It has long been recognized that course and efficiency of a chemical reaction is largely mediated by the short-lived transient species (excited state or radicals) which are formed as reactive intermediates during a chemical ...
Nature Of Solute-Solvent Interaction : Effect Of Solvent Polarity On Excited State Structure Of 2,2,2-Trifluroacetophenone And Effect Of Hydrogen Bonding In Hydrated Electron Absorption Spectrum
(2009-09-02)
In solution, the environment around the solute is determined solely by the solvent molecules, which are present closer to the solute. This interaction between solute and solvent shell is very crucial for equilibrium structure ...
Modeling Electronic Properties Of Strongly Correlated Conjugated Molecular Systems
(2015-08-17)
Organic conjugated systems are attractive because of wide range of applications, which includes stimulated emission from -conjugated polymers, optical switches, organic solar cells and organic light emitting diodes, to ...
Relationship Between Pressure And Size Dependence Of Ionic Conductivity In Aqueous Solutions And Other Studies
(2013-08-02)
Diffusion is a fundamental process which plays a crucial role in many processes occurring in nature. It is governed by the Fickian laws of diffusion. The laws of diffusion explain how diffusive flux is related to the ...
Gas Phase And Electrocatalytic Reaction Over Pt, Pd Ions Substituted CeO2, TiO2 Catalysts and Electronic Interaction Between Noble Metal Ions And The Reducible Oxide
(2010-06-02)
Among the various heterogeneous catalytic reactions three way catalysis (TWC), catalytic combustion of hydrogen, water gas shift reaction (WGS) and preferential oxidation of CO (PROX) in the hydrogen rich stream are some ...