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N-Heterocyclic Carbene (NHC)-Catalyzed Stereoselective Synthesis of Six-Membered Heterocycles and Carbocycles
N-Heterocyclic carbene (NHC) based catalysis is employed for the generation of α,β-unsaturated acylazoliums followed by their interception with various nucleophiles, the formal [3+3] annulation reactions for the construction ... -
N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of Dihydrothiopyranones, Functionalized Benzofurans and Extending Michael Acceptor Aldimine Umpolung
Carbenes exhibit high reactivity as divalent species with six electrons in their valence shell. Their electrophilic nature arises from an incomplete octet. However, when a heteroatom is introduced adjacent to the carbene ... -
N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of C-O Axially Chiral Diaryl Ethers, Tricyclic Lactones and Lactams
N-heterocyclic carbene (NHC)-catalyzed transformations with distinctive activation modes allow the facile synthesis of atropoisomers. In this context, we have demonstrated the NHC-catalyzed synthesis of axially chiral diaryl ... -
N-Heterocyclic Carbene-Catalyzed Synthesis of Oxazolones, e-Lactones and N-N Axially Chiral Molecules
The diverse reactivity of N-heterocyclic carbenes (NHCs) in organocatalysis is due to the possibility of different modes of action. Although NHC-bound enolates and dienolates were well-known, the NHC-bound cross-conjugated ... -
Nano Porous Alumina Based Composite Coating for Tribological Applications
(2018-02-06)Anodisation is a surface treatment process, commonly used to form a protective oxide coating on the surface of metals like aluminium. Anodised coatings, being grown out of the base metal have excellent interface strength ... -
Nano Surface Modifications for Anti-Corrosive and Anti-Biofouling Applications
Microbially Induced Corrosion (MIC) of materials is a major concern of marine industry. Various ferrous and non-ferrous materials used in industry are prone to MIC. Bio-fouling or formation of bio-film on material surface ... -
Nano-mechanical, optical and structural property correlations in binary, ternary, and quaternary tellurium-based chalcogenide glasses
Over a half century, from the advent of chalcogenide glasses, it was used for various applications like xerography, phase change memories (PCM), solar cells, infrared devices and so on. These applications made use of some ... -
Nano-Scale Design, Fabrication, and Performance Evaluation of Organic Photovoltaic Devices
Organic photovoltaic devices have evinced interest due to the prospects of integrating strongly absorbing semiconducting polymers in flexible, light weight device platforms with ease of fabrication. However, there are ... -
Nanocrystalline Titania Based Dye Sensitized Solar Cells - Effect Of Electrodes And Electrolyte On The Performance
(2015-07-22)Dye-sensitized solar cells (DSC) have attracted considerable scientific and industrial interest during the past decade as an economically feasible alternative to conventional photovoltaic devices. DSCs have the potential ... -
Nanodevices of Graphene, Carbon Nanotubes and Flow Behaviour of Graphene Oxide Gel
(2018-05-09)In the last three decades carbon nanomaterials such as fullerenes, carbon nanotubes and graphene have attracted significant attention from the scientific community due to their unique electronic, optical, thermal, mechanical ... -
Nanomaterials for Magnetism and Catalysis
Nanomaterials possess unique physical and chemical properties allowing for advancement and innovation in diverse scientific and technological fields. The remarkable magnetic and catalytic properties of these nanomaterials ... -
Nanoparticle Mediated Suppression of Protein Aggregation
(2018-05-11)The increasing demands for biopharmaceuticals to treat different diseases have raised concerns about controlling the quality and efficacy of such pharmaceuticals. The design and formulation of a stable protein or peptide ... -
Nanoparticles for Bio-Imaging : Magnetic Resonance Imaging and Fluorescence Imaging
(2018-07-19)This thesis provides several nanomaterial systems that can be used as contrast agents in magnetic resonance imaging (MRI) and for optical fluorescence imaging. Nanoparticle systems described in this thesis fall under three ... -
NanoPhotoCatalysis: A New Dimension in Synthetic Chemistry
Photocatalysis has emerged as a powerful tool in recent years to drive chemical transformations via electron/energy transfer, allowing access to several unstable or high energy intermediates. Thus, the design and ... -
Nanopore Based Single-molecule Sensors
In the past two decades nanopores have been used as highly sensitive detection systems for exploring the properties of analytes at single molecule resolution. The small dimensions of a nanopore permit the molecule of ... -
Nanoscale spatial and temporal response of lipid membranes interacting with biomolecules and nanoparticles
The cell membrane is the first point of interaction whenever any external biomolecule or nanoparticle encounters a cell. Thus the nature of interactions between the cell membrane and various proteins, nanoparticles, and ... -
Nanoscale surface engineering of metallic biomaterials for enhancement of mechanical and biological responses
Metallic materials are widely used in load bearing orthopedic applications. The alloys used in the implants are 316L stainless steel (SS), commercially pure Ti (cp-Ti), Ti-6Al-4V and Co-Cr-Mo alloys. The life of implants ... -
Nanostructured Assemblies Based On Metal Colloids And Monolayers: Preparation, Characterisation And Studies Towards Novel Applications
(Indian Institute of Science, 2005-12-08)Nanoscience dominates virtually every field of science and technology in the 21st century. Nanoparticles are of fundamental interest since they possess unique size- dependent properties (optical, electrical, mechanical, ...