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Enantioselective Annulation Reactions: From Fischer Indolization to de novo Arene Construction
In summary, we have developed the first decarboxylative [4+2]-annulation of ethynyl
benzoxazinanones with azlactones for the enantioselective synthesis of cyclic α-quaternary
α-acylaminoamides.25 This direct and modular ...
Construction of C-C Bonds by Photocatalysis via Radical Addition Cascade Cyclization (RACC): Synthesis of Heteroatom-Containing Small Molecules
The thesis presents photocatalytic methods for synthesizing small organic molecules at room temperature. The thesis is divided into four sections. Section A presents the general introduction to the thesis. Section B is ...
Studies on Mono- and Multi-valent Ion Storage Using Metal Phosphosulfide and Organic Carbonyl Compounds
The present study describes the results on inorganic and organic materials for energy
storage and sensors. It contains eight chapters including introduction, experimental and
summary sections. The first chapter gives ...
Metal Ion Mediated Riboswitch Folding and Cognate Ligand Sensing
Riboswitches are noncoding RNA molecules that can control gene expression upon cognate ligand binding. Riboswitches are primarily present in bacteria and are crucial for bacteria's survival, which makes riboswitches ...
Developing a tunable, adaptive plasmid selection system to screen Aminoacyl-tRNA synthetase variants
The genetic code refers to a set of rules used by living organisms to translate information encoded within the genetic material (DNA/mRNA sequences) into proteins. All organisms generally encode 22 proteinogenic or canonical ...
Investigation of Psychrophilic SUMO Proteases: Towards a More Efficient SUMO Protease at Lower Temperature
Covalent attachment of the fusion protein, Small Ubiquitin-like modifier (SUMO), to recalcitrant
target proteins (especially transmembrane proteins) make purification of the target protein much
easier by enhancing its ...
Thermodynamics of Protein Adsorption on Gold and Silica Nanoparticles
Nanoparticle-based biomedical applications in disease diagnostics, site targeting, drug
delivery, etc., have been pursued vigorously with the hope of finding better solutions than
conventional diagnostics and therapeutics. ...
Enabling Lithium Metal Anode for Garnet Electrolyte based Solid State Batteries
Solid-state lithium metal batteries (SSLMB) employing inorganic solid electrolytes (ISE) in conjunction with lithium metal anode and intercalation cathode are considered among the most promising alternatives for Li-ion ...
N-Heterocyclic Carbene-Catalyzed Synthesis of Oxazolones, e-Lactones and N-N Axially Chiral Molecules
The diverse reactivity of N-heterocyclic carbenes (NHCs) in organocatalysis is due to the possibility of different modes of action. Although NHC-bound enolates and dienolates were well-known, the NHC-bound cross-conjugated ...
Self-Assembled Coordination Architectures for Fluorescence Modulation, Photocatalysis, and Light Harvesting
Self-assembly and noncovalent interactions play a pivotal role in the design of complex, and
intricate functional structures. Among several design approaches, metal-ligand coordinationdriven self-assembly has emerged as ...