Browsing Division of Chemical Sciences by Title
Now showing items 549-568 of 894
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Rational Design of Diketopyrrolopyrrole-Based Conjugated Polymers for Ambipolar Charge Transport
(2018-04-12)The present thesis is focused on the rational design of Diketopyrrolopyrrole based π- conjugated polymers for organic electronics. The thesis is organized into six different chapters and a brief description of the individual ... -
Rational Design of Efficient Catalysts using First-Principles and Machine Learning
Rising concerns about the impending energy crisis and environmental impact have garnered tremendous research interest in developing catalysts for sustainable fuel production and pollution abatement. However, the traditional ... -
Rational Designing of Bifunctional Electrocatalysts for Electrochemical Energy Conversion and Storage Devices
Depleting fossil fuels, increasing environmental concerned and looming energy crisis motivates researcher around the globe to explore some of the possible eco-friendly energy alternative resources. Among various available ... -
Rational Synthesis, Stabilization, and Functional Properties of Metal and Intermetallic Nanoparticles
(2018-04-11)The confluence of intriguing size and morphology dependent optical and chemical properties with versatile application in various fields, such as energetic and magnetic makes monometallic nonmaterial of high fundamental ... -
Real-Time DMRG Dynamics Of Spin And Charge Transport In Low-Dimensional Strongly Correlated Fermionic Systems
(2014-12-11)This thesis deals with out-of-equilibrium transport phenomena in strongly correlated low-dimensional fermionic systems, with special emphasis on π-conjugated molecular materials. The focus of this work is to study real-time ... -
Reductive And Metathetic Coupling Reactions Mediated By Group (IV) Metal Alkoxides
(2010-10-19)Several organic transformations are mediated by group(IV) metal alkoxides. The reactivity is based on the basic nature of alkoxide group, Lewis acidic nature of the group(IV) metals, insertion of unsaturated molecules into ... -
Regioselective C-H Amidation Reactions using Directing Group Strategy and its Application in Organic Synthesis
The thesis represents an approach for the C-H bond activation using directing group strategy. The C-H activation happens through five/six-membered metallacycle through concerted metallation deprotonation. Further ... -
Regioselective Functionalization of Indoles using Directing Group Strategy : An Efficient Transition Metal Catalysis
(2018-02-07)The thesis entitled “Regioselective Functionalization of Indoles using Directing Group Strategy: An Efficient Transition Metal Catalysis” is divided into two sections. Section A, which is presented in three chapters, ... -
Relationship Between Pressure And Size Dependence Of Ionic Conductivity In Aqueous Solutions And Other Studies
(2013-08-02)Diffusion is a fundamental process which plays a crucial role in many processes occurring in nature. It is governed by the Fickian laws of diffusion. The laws of diffusion explain how diffusive flux is related to the ... -
Resonance Energy Transfer Using ZnO Nanocrystals And Magnetism In The Mixed Metal Layered Thiophosphates, Mn1-xFexPS3(0≤x≥1)
(2013-07-26)This thesis consists of two parts. The first part deals with the visible emission of ZnO Nanocrystals and its possible application in Resonance Energy Transfer (RET) studies. The second part of the thesis is on the magnetic ... -
Reversible Redox Switching of First Hyperpolarizability (Β) of Metallorganic Complexes
The concept of molecular switches has garnered enormous interest because of the vital role of these switches as components in molecular electronic/photonic devices, signal transmission and optical communication. Compounds ... -
The Role of Liposomal Hybrids and Gold Nanoparticles in the Efficacious Transport of Nucleic Acids and Small Molecular Drugs for Cancer Nanomedicine
(2018-07-23)The thesis entitled “The Role of Liposomal Hybrids and Gold Nanoparticles in the Efficacious Transport of Nucleic Acids and Small Molecular Drugs for Cancer Nanomedicine” elucidates the preparation of various liposomal ... -
Role of spin density and interchromophoric coupling in singlet fission
Singlet exciton fission (SEF) is the transformation of a photoexcited singlet exciton into two triplets localized on two chromophores coupled together. This process therefore produces two triplet excitons at the expense ... -
Room Temperature Molten Liquids Based On Amides : Electrolytes For Rechargeable Batteries, Capacitors And Medium For Nanostructures
(2011-01-10)Room temperature molten liquids are proposed to be good alternates for volatile and harmful organic compounds. They are useful in varied areas of applications ranging from synthesis, catalysis to energy storage molten ... -
Room Temperature Phosphorescence and Circularly Polarized Luminescence Characteristics of Phosphine Oxides and Phosphoramides
Room temperature phosphorescence (RTP) materials have attracted much attention in recent years owing to their potential applications in organic light-emitting diodes (OLEDs), security writing, time-gated bio-imaging, ... -
Rotational Specroscopic And Theoretical Investigations Of Non-conventional Hydrogen Bonds
(2014-11-12)The nature of interactions within a molecule, i.e. chemical bonding, is well understood today. However, our understanding about intermolecular interactions, which has great relevance in nature, is still evolving. Historically ... -
Rotational Spectroscopic And Ab Initio Studies On The Weakly Bound Complexes Containing 0-H...π And S-H...π Interactions
(2010-11-22)Work reported in this thesis mainly comprises of the assignments and analysis of the rotational spectra and structures of three weakly bound complexes: C2H4•••H2S, C6H5CCH•••H2O and C6H5CCH•••H2S. All the data have been ... -
Rotational Spectroscopic and Computational Studies on Inter/Intramolecular Bonding
The importance of non-covalent interactions cannot be undermined, as it permeates nearly every sphere of chemistry. The hydrogen bond is the most well-known and ubiquitous non-covalent interaction. In recent times similar ... -
Ru (II)-Catalyzed C−H Activation: Amide-Directed 1,4-Addition of Ortho C−H Bond to Maleimides
Transition metal catalyzed functionalization of C-H bond to C-C bond is advantageous and atom economical. The use of directing groups is intended to overcome the challenges associated with the C-H activation such as low ...