Browsing Division of Chemical Sciences by Title
Now showing items 115-134 of 1498
-
Chemistry Of Thio And Seleno Metallates In Organic Synthesis
(2007-12-29)Thio metallates are known for many years for their utility in many processes. They have been established as versatile reagents in organic synthesis. However the heavier metal chalcogenides, though known for many years, ... -
Chiral Bisphosphinites For Asymmetric Catalysis
(2010-07-21)Chiral bisphosphinites are well-documented alternatives for chiral bisphosphines as ligands that can be exploited in various asymmpetric syntheses. Particularly, vicinal biarylphophinite ligands give a seven membered chelate ... -
Chiral pool based approach for the synthesis of bio-active lactones and 1,2-aminoalcohols
Synthesis of 10-membered bioactive lactone microcarpalide (I), (2S,3R)-2-aminododecan-3-ol (II), and Xestoaminol C (III) from inexpensive chiral pool sources such as tartaric acid and L-(+)-alanine was described. The ... -
Cholic acid based new chiral auxiliaries: development and applications
(Indian Institute of Science, 2005-04-25)The thesis entitled Cholic Acid Bused New Chiral Auxiliaries: Development And Applications has been divided into three chapters. Chapter-I describes the synthesis of chiral auxiliaries (1.3) from cholic acid and Diets-Alder ... -
Co-solvent Induced Protein Collapse and Folding
An unfolded protein under favorable conditions navigates its complex energy landscape on a time scale of milliseconds to seconds and folds into a specific three dimensional structure. The mechanism of protein folding is ... -
Cobalt-nhc Complexes and Diazabutadienes in Activation of Mono/Diboron Compounds and Their Application in C-b Coupling Reactions
Boronic acid(esters) have been well recognized as an indispensable coupling partner in the Suzuki-Miyaura cross coupling reactions producing a vast spectrum of molecules, applicable in the diverse field ranging from medicinal ... -
Cocrystallization Studies Extending from Small Molecules to Proteins: a) Cocrystals, Salts and Eutectics, b) Chemical, Structural and Biological Evaluation of Anthrapyrazolones as Inhibitors of JNK proteins
In summary, we have designed and synthesized three halogenated derivatives of 1,9- pyrazoloanthrone. The involvement of halogen bonding provides highly directional interactions in the binding pocket and hence demonstrates ... -
Combusition of polymers and the effect of fore retardant additives : a mechanistic approach.
CHAPTER 1 This chapter constitutes a general description of the combustion of polymers and the various processes involved. Processes like gas‑phase reactions, surface reactions and solid‑phase reactions are discussed in ... -
Combustion synthesis and properties of ferroelectrics, relaxor ferroelectrics & microwave resonator materials
Dielectric materials include ferroelectrics, relaxor ferroelectrics and microwave resonators which are classified on the basis of their dielectric performances like dielectric constant, dielectric loss and piezoelectric ... -
Combustion synthesis and properties of fine particle oxide materials: studies on Ferrites
Synthesis of oxide materials with desired structure and properties is of prime importance in Solid State Chemistry and Materials Science. Since the discovery of superconductivity in oxide ceramics, there has been renewed ... -
Combustion synthesis and properties of fine particles spinel, Perovskite and K2NiF4 Type oxides
Technologically important fine?particle, mixed?metal, transition?metal oxides such as spinels (MCr?O?), perovskites (LnCrO?, La(Sr)MnO?, LaCoO? and LaNiO?) and K?NiF??type oxides (La?CoO?, La?NiO?, La?CuO? and La?.?Sr?.?CuO?) ... -
Combustion synthesis and properties of nanosize oxides : studies on solid oxide fuel cell materials
Salient Features The low?temperature initiated, self?propagating, and gas?producing combustion process, developed and used for the preparation of technologically important oxide materials, has now been successfully extended ... -
Complex plane and D.C. polarographic behaviour of zinc and cadmium in ethanolemine
Abstract not available -
Complex plane and DC polarographic studies of lead (11) ethanolamine (mono-D1 and TR1-) systems
A detailed investigation on the polarographic (d.c. and complex plane) behavior of lead ion in sodium perchlorate, potassium nitrate, potassium chloride, ethanolammonium (mono-, di-, and tri-) perchlorates and the respective ... -
Computational Modeling of two Dimensional Heterostructures for Optoelectronic and Catalytic Applications
Two-dimensional van der Waals (2D-vdW) materials have attracted significant attention for their unique and excellent properties. The properties of the 2D-vdW materials can be precisely engineered using various techniques ... -
Computational Studies of Heavier Main Group Elements: Control of Lewis Acidity of Bi and Sb by Charge and Ligand Design, and Structural Variations of [Fe(CO)4]2E2 and E2CH2 Isomers (E = C–Pb)
Traditional main group compounds demonstrate Lewis acidity due to the presence of vacant p- orbitals. Hydrides of lighter main group elements, such as NH3, function as Lewis bases. However, introducing highly electronegative ... -
Computational Studies of Hydrophobic Force Law, Dynamics in Model Asymmetric Binary Mixtures, and Contribution to One and Two Dimensional Infrared Spectroscopy
Depending on the system and phenomena of interest, the thesis has been partitioned into three major parts. The first part is on the theoretical infrared spectroscopic studies and vibrational phase relaxation of supercritical ... -
Computational studies of the effect of confinement in Zeolitic cavities on the diffusion of monatomic Sorbates and the melting characteristics of Argon Clusters
The present chapter has attempted to study the temperature dependence of the levitation effect. It has been shown that this effect is most pronounced at lower temperatures and decreases in intensity at higher temperatures. ... -
Computational Studies of the Electronic Structures and Ring Contraction Reactions of Pn (n=4-6) Ring in Double and Triple Decker Complexes, and an Orbital Engineering Approach to Stabilise Borozene (B6H6)
The well established chemistry of ferrocene1-3 and different sandwich scaffolds4,5 with organic rings prompted us to explore the electronic structures and reactivity of sandwich complexes involving inorganic rings, i.e., ... -
Computational Studies on Interstellar Molecular Species : From Formation to Detection
(2018-03-01)Initiated with the purpose of assigning the Fraunhofer lines in the solar spectrum to atomic transitions in the 18th century, the collaboration between spectroscopists and astrophysicists has remained fruitful, successful ...