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Cholic acid based new chiral auxiliaries: development and applications
(Indian Institute of Science, 2005-04-25)
The thesis entitled Cholic Acid Bused New Chiral Auxiliaries: Development And Applications has been divided into three chapters. Chapter-I describes the synthesis of chiral auxiliaries (1.3) from cholic acid and Diets-Alder ...
Asymmetric Synthesis Of Troger's Base Analogues And Studies In Molecular Recognition
(Indian Institute of Science, 2005-04-25)
Troger's base was the first amine to be resolved where the chirality was due to solely very high inversion barrier around nitrogen atom. Though the molecule was known for over a century, work done during the past decade ...
Studies on N-Heterocyclic Compounds
(Indian Institute of Science, 2005-04-27)
The thesis entitled "Studies on N-Hetero cyclic Compounds: (a) Reaction of 5,6,7,8-Tetrahydroisoquinolines with Vilsmeier Reagent and (b) Amide Induced in situ Alkylation of 5,6-Dihydroisoquinolines" is presented in two ...
Theoretical Studies Of pie-Facial Selectivity In Organic Reactions
(Indian Institute of Science, 2005-06-15)
he thesis entitled "Theoretical Studies of pie-Facial Selectivity in Organic Reactions" involve a computational examination of a suitable reactivity problem in organic chemistry. Systematic and efficient -procedures have ...
Norbornyl System Revisited : Exploring A Versatile Building Block For The Syntheses Of Natural Products And Analogues
(2009-03-11)
Carbohydrates are ubiquitous and important biomolecules. Initially thought to be dull, energy storing moieties, the importance of carbohydrates and their conjugates, glycoproteins and glycopilids, in cellular communication ...
Enantioselective Synthesis Of Bio-Active Bicyclic Acetals, Cyclic Ethers And Lactones
(2009-07-09)
The thesis entitled “Enantioselective synthesis of bio-active bicyclic acetals, cyclic ethers and lactones” demonstrates the utility of chiral pool tartaric acid as the source in the synthesis of natural products. The ...
Synthetic investigations on terpenoids
(Indian Institute of Science, 2005-04-27)
The thesis entitled "Synthetic Investigations on Terpenoids" is divided into two sections. Section 1 deals with the total synthesis of sesquiterpenes belonging to the Zizsene group and Section 2 contains the synthetic ...
Computational Studies On Some Plausible Structures Of The Hydrides And Oxyhydrides Of [36-D6h] Fullerene
(Indian Institute of Science, 2006-11-23)
Fullerenes, the highly symmetric molecular carbon clusters, have been in the limelight of scientific research since their discovery by Kroto and coworkers [1]. The focus of experimental and theoretical studies has centered ...
Bile Acid Based Molecular Tweezers And Crown Ethers
(Indian Institute of Science, 2005-05-02)
Chapter 1. Introduction to Molecular Tweezers
Whitlock and Zimmerman developed a class of molecular hosts, popularly known as molecular tweezers, which sandwich aromatic guests by ii=ii interaction. Chapter 1 summarizes ...
Organosulfur Reactions In Organic Synthesis With Tetrathiomolybdate
(Indian Institute of Science, 2005-04-27)
Recent years have seen a dramatic expansion in synthetic and structural molybdenum - sulfur chemistry. The amplest binary Mo-S moiety in MO$ ion. The thromolybdates derived by sulfur substitution from the 0x0 analogue have ...