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Design and Synthesis of Peptidomimics Constrained in Helical and Sheet Conformations using a Novel Covalent Surrogate for the Peptide Main Chain Hydrogen Bond
(2018-07-20)
This thesis entitled “Design and Synthesis of Peptidomimics Constrained in Helical and Sheet Conformations Using a Novel Covalent Surrogate for the Peptide Main Chain Hydrogen Bond” is divided into six chapters.
Chapter ...
Alkynones Derived from Tartaric Acid : Efficient Building Blocks for the Synthesis of Macrolactone Natural Products
(2018-07-05)
The thesis describes the synthesis and application of various alkynones derived from the bis-Weinreb amide of tartaric acid in the total synthesis of macrolactone natural products. The thesis is divided into three sections. ...
Synthesis, Conformation and Glycosidic Bond Stabilities of Septanoside Sugars
(2017-12-12)
Seven-membered cyclic sugars, namely, septanoses and septanosides, are less commonly known sugar homologues. Synthesis of septanoses arise an interest due to their configurational and conformational features and the ...
Enantiospecific Synthesis Of Silphiperfolane, Basmane And Fusicoccanes
(2016-10-20)
Nature’s expertise and virtuosity in creating a phenomenal array of carbocyclic
frameworks finds its full expression in the terpenoid group of natural products. The total synthesis of natural products frequently provided ...
Bile Acid based Supramolecular Gels, Soft Hybrid Materials and their Applications
(2017-12-16)
Chapter 1. Supramolecular Gels and their Applications
Supramolecular gels are viscoelastic materials composed of a solid like three dimensional fibrillary network that is embedded in a liquid. Supramolecular gels are derived ...
Lanthanide Based Hydrogels in Sensing, Energy Transfer and Nanoparticle Synthesis
(2018-01-04)
Chapter 1: Luminescence property of lanthanide and its applications
Lanthanides are well-known for their unique luminescence property and have found widespread applications in sensing, bioimaging, lasers, optoelectronic ...
Total Synthesis of Bio-active Natural Products Gabosines, Crassalactone C, Anamarine and Iriomoteolide 3a
(2018-01-03)
First chapter of the thesis describes the desymmetrization of the bis-dimethyl amide 1 derived from tartaric acid with vinyl Grignard reagents and subsequent reduction of the resultant -keto amides 2a-c to the -hydroxy ...
Stereochemical And Synthetic Investigations
(2017-05-25)
PART I
RESOLUTION AND DESYMMETRISATION
Chapter I. ‘A Novel Racemate Resolution’. This describes a novel resolution strategy as applied to racemic α-amino acids in the solid state. The strategy is based on the possibility ...