Search
Now showing items 1-5 of 5
Gas Phase And Electrocatalytic Reaction Over Pt, Pd Ions Substituted CeO2, TiO2 Catalysts and Electronic Interaction Between Noble Metal Ions And The Reducible Oxide
(2010-06-02)
Among the various heterogeneous catalytic reactions three way catalysis (TWC), catalytic combustion of hydrogen, water gas shift reaction (WGS) and preferential oxidation of CO (PROX) in the hydrogen rich stream are some ...
Reductive And Metathetic Coupling Reactions Mediated By Group (IV) Metal Alkoxides
(2010-10-19)
Several organic transformations are mediated by group(IV) metal alkoxides. The reactivity is based on the basic nature of alkoxide group, Lewis acidic nature of the group(IV) metals, insertion of unsaturated molecules into ...
Studies Of MnO2 As Active Material For Electrochemical Supercapacitors
(2010-11-02)
Electrical double-layer formed at the interface between an electrode and an electrolyte has been a topic of innumerable studies. The electrical interface plays a crucial role in kinetics, mechanisms and applications in ...
Chiral Bisphosphinites For Asymmetric Catalysis
(2010-07-21)
Chiral bisphosphinites are well-documented alternatives for chiral bisphosphines as ligands that can be exploited in various asymmpetric syntheses. Particularly, vicinal biarylphophinite ligands give a seven membered chelate ...
Mapping The Reaction Coordinate For The Oxidative Addition Of Molecular Hydrogen To A Metal Center
(2010-07-15)
The binding of molecular hydrogen to a metal center leads to the elongation of the H−H bond and subsequently to its cleavage along the reaction coordinate for the oxidative addition of H2. There has been considerable ...