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Theoretical Approaches to the Study of Fluctuation Phenomena in Various Polymeric Systems
(2018-04-05)
The goal of this thesis has been to throw light on a selection of open problems in chemical and biological physics using the general principles of statistical mechanics. These problems are all broadly concerned with the ...
Hyperbranched Polyacetals and Polydithioacetals
(2018-04-23)
Dendrimers are a class of perfectly branched symmetric monodisperse macromolecules, which are synthesized using a stepwise procedure. Due to their highly symmetric structure, they possess a definite core, discrete generations ...
Understanding the Structure, Bonding and Reactivity of Unsaturated Metallacycles : A Computational Study
(2018-04-05)
Stabilization of highly strained organic species and altering normal reactivity norms of organic fragments by transition metals have been a triumphing feat of organometallic chemistry. A variety of saturated and unsaturated ...
Mechanistic Investigation of Metal Promoted Nucleophilic Additions
(2017-11-30)
Nucleophilic additions are an important class of reactions in the preparation of several organic compounds. Metals facilitate nucleophilic additions in many cases. The present work Mechanistic Investigation of Metal Promoted ...
Studies on Poly(p-phenylene Vinylene) [PPV] Derivatives : Conjugation Length Control and Nanoparticle Preparation and Utilization
(2018-03-09)
The study of conjugated polymers, in particular PPV derivatives, continues to fascinate researchers both from the standpoint of developing new routes to control their structure and photophysical properties; this is also ...
Self-Selection Of Discrete Molecular Architectures In Coordination-Driven Self-Assembly
(2016-10-20)
Self–assembly has long been attracting chemists’ attention because it can yield fascinating supramolecular architectures in a single step. More precisely, metal–ligand coordination–driven self–assembly has stood out as an ...
Self-Assembly Of Functional Supramolecular Architectures via Metal-Ligand Coordination
(2015-09-09)
Over the past few decades, supramolecular self-assembly has become an alternative synthetic tool for constructing targeted discrete molecular architectures. Among various interactions, metal-ligand coordination has attracted ...
Functionalized Hyperbranched Polymers And Nonionenes
(2016-10-20)
In 1980’s a new class of material named as dendrimer became popular both in the field of polymer science and engineering. Dendrimer is an example of symmetric, highly branched three dimensional globular nano-object. It ...
Dynamics Of Activated Processes Involving Chain Molecules
(2009-09-11)
This thesis presents our recent study of few interesting problems involving activated processes. This chapter gives an overview of the thesis.
It is now possible to do single molecule experiments involving enzyme molecules. ...
Conformational Reorganization Of Hyperbranched And Linear Polymers And Functionalized Porous Polymer Films
(2014-04-22)
The main focus of the research work presented in the thesis is the understanding of structural and conformational reorganizations in hyperbranched and linear polymers. The thesis includes three different investigations: ...