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Synthesis And Investigation Of Transition Metal Oxides Towards Realization Of Novel Materials Properties
(Indian Institute of Science, 2007-03-23)
Transition metal compounds, especially the oxides, containing dn (0 ≤ n ≤ 10) electronic configuration, constitute the backbone of solid state/materials chemistry aimed at realization of novel materials properties of ...
Diffusion In Porous Solids : Void Disorder, Orientation And Rotation, Reaction And Separation, And Levitation Effect
(Indian Institute of Science, 2006-12-12)
Diffusion in bulk has been well studied and our understanding may be said to be adequate if not complete. Similarly, surface diffusion has been investigated by a number of workers and a fair understanding of it has emerged. ...
Structure, Organization And Phase Transitions In Anchored Alkyl Chain Bilayers In Layered Organic-Inorganic Hybrids
(2009-04-09)
This thesis deals with the conformation and phase-transitions in anchored alkyl chain bilayer assemblies in organic-inorganic hybrids. The alkyl chain bilayers in organic-inorganic hybrids bear a striking resemblances to ...
Quadratic Nonlinearity In Covalently And Non-Covalently Linked Molecules In Solution
(2008-10-01)
This thesis deals with the investigation of the first hyperpolarizabilities (β) of a large number of molecules linked to other molecules either covalently or noncovalently. Chapter 1 gives a brief
introduction to ...
Theoretical Investigations On A Few Biomolecular Rate Processes
(2008-10-14)
Traditional topics such as physics, chemistry and mathematics have immensely changed the world in the twentieth century, but the twenty-first century seems to be that of soft condensed matter physics, which has already ...
Phosphorus(III) Ligands Based On The P-N-P Skeleton And Their Transition Metal Complexes
(2009-06-05)
There is considerable current interest in the design and synthesis of new phosphorus ligands and their transition metal complexes in view of their potential applications in homogeneous catalysis. The present study is ...
Ruthenium Complexes Of Chiral And Achiral Phosphorus Ligands Based On The P-N-P Motif
(2007-09-05)
In recent years there is an increasing awareness of the importance of chiral phosphorus ligands in transition metal organometallic chemistry because of the utility of such complexes in homogeneous catalytic reactions. This ...
Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes
(Indian Institute of Science, 2007-06-22)
The bite angle of a diphosphine ligand plays an important role in determining the reactivity of a transition metal complex. The coordinated dihydrogen on a transition metal center can be activated toward homolysis or ...
Organically-Templated Open-Framework And Hybrid Materials
(2008-01-25)
Open-framework inorganic and inorganic-organic hybrid materials constitute an important area of study in materials chemistry, because of their potential applications in areas such as sorption and catalysis. Besides ...
Biomimetic Studies On Anti-Thyroid Drugs And Thyroid Hormone Synthesis
(2009-05-22)
Thyroxine (T4), the main secretory hormone of the thyroid gland, is produced on thyroglobulin by thyroid peroxidase (TPO)/hydrogen peroxide/iodide system. The synthesis of T4 by TPO involves two independent steps: iodination ...