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dc.contributor.advisorPrabhu, K R
dc.contributor.authorBettadapur, Kiran R
dc.date.accessioned2018-11-06T09:44:39Z
dc.date.available2018-11-06T09:44:39Z
dc.date.submitted2017
dc.identifier.urihttp://etd.iisc.ac.in/handle/2005/4134
dc.description.abstractThe thesis entitled “Site-selective C-H Functionalization using Directing Group Strategy via C-H Bond Activation” is divided into two sections. Section A, is presented in four chapters, comprising the work on the aromatic ortho-C-H addition to maleimide, mechanistic studies with DFT, ortho-C-H oxidative Heck reaction with maleimides, and ortho-C-H addition to maleimide with a deciduous/traceless directing group. Section B describes a formal oxidative [2+2+2] benzannulation of indoles with alkynes via a directing group strategy. Publications: 1. Ru (II)-Catalyzed C–H Activation: Ketone-Directed Novel 1, 4-Addition of Ortho C–H Bond to Maleimides KR Bettadapur, V Lanke, KR Prabhu; Org. Lett., 2015, 17, 4658-4661 2. A Deciduous Directing Group Approach for the Addition of Aryl and Vinyl nucleophiles to Maleimides KR Bettadapur, V Lanke, KR Prabhu; Chem. Comm., 2017, 53, 6251-6254 3. Weak Directing Group Steered Formal [2+2+2]- Oxidative Cycloaddition for Selective Benzannulation of Indoles KR Bettadapur, R Kapanaiah, V Lanke and KR Prabhu; J. Org. Chem., DOI: 10.1021/acs.joc.7b02719en_US
dc.language.isoen_USen_US
dc.relation.ispartofseriesG28634;
dc.rightsI grant Indian Institute of Science the right to archive and to make available my thesis or dissertation in whole or in part in all forms of media, now hereafter known. I retain all proprietary rights, such as patent rights. I also retain the right to use in future works (such as articles or books) all or part of this thesis or dissertationen_US
dc.subjectC-H Bond Activationen_US
dc.subjectC-H Functionalizationen_US
dc.subjectMaleimidesen_US
dc.subjectC–H Bond - Maleimidesen_US
dc.subjectRh(III)-Catalyzed C-H Activationen_US
dc.subjectIndolesen_US
dc.subjectMaleimideen_US
dc.subjectIndoleen_US
dc.subject.classificationOrganic Chemistryen_US
dc.titleSite-selective C-H Functionalization using Directing Group Strategy via C-H Bond Activationen_US
dc.typeThesisen_US
dc.degree.namePhDen_US
dc.degree.levelDoctoralen_US
dc.degree.grantorIndian Institute of Scienceen_US
dc.degree.disciplineFaculty of Scienceen_US


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