Browsing Division of Chemical Sciences by thesis submitted date"2021"
Now showing items 1-20 of 49
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Allylic Halogenation Route to Latent-Active Trans-Glycosylation of Allyl Glycoside Donors
Allylic halogenation of allyl glycosides as a new route to allyl glycoside donors in glycosylations is investigated in this thesis. Allyl functionality is one of the commonly adopted protecting groups to hydroxyl groups ... -
Analytical Applications of Bile Acid-derived Soft Materials
Supramolecular gels are soft materials with solid-like properties such as supporting weight and retaining shape; and some liquid-like features which make them injectable, printable, etc. On the other hand, lanthanide-based ... -
Analytical models of selected stochastic processes in condensed phase systems
This thesis is a record of the research I have carried out over the last five years to understand a selection of problems in the broad area of single-molecule physics. These problems cover four broad themes: (i) dynamically ... -
Aqueous Binary Mixtures: A Study Using NMR Measurements and ab initio Molecular Dynamics Simulations
Binary mixtures having a combination of hydrophobic and hydrophilic groups, such as waterdimethyl sulfoxide (DMSO), water-methanol, water-ethanol, water-tertiary butyl alcohol (TBA), water dioxane, and water-glycerol, ... -
Cobalt-nhc Complexes and Diazabutadienes in Activation of Mono/Diboron Compounds and Their Application in C-b Coupling Reactions
Boronic acid(esters) have been well recognized as an indispensable coupling partner in the Suzuki-Miyaura cross coupling reactions producing a vast spectrum of molecules, applicable in the diverse field ranging from medicinal ... -
Constructing transition metal-based heterostructure nanomaterials for electrocatalysis
Storing renewable energy into chemical bonds like hydrogen as a carbon-neutral energy carrier to deliver the energy demands is gaining attention. However, the popular hydrogen production route by water electrolysis involves ... -
Construction of C-C bonds by C-H Activation: Rh(III)-Catalyzed reactions of Arenes and Heteroarenes with Maleimides and Allylic Alcohols
The thesis presents a few Rh-catalyzed C-H activations for the construction of C-C bonds. The difficulty of substitution or the arylation at the maleimide's double bond under C-H activation conditions prompted a detailed ... -
Construction of Carbon-Heteroatom and Heteroatom-Heteroatom bonds using Iodine and Zinc catalysts
The thesis entitled “Construction of Carbon-Heteroatom and Heteroatom-Heteroatom bonds using Iodine and Zinc catalysts” has been divided into five chapters. Chapter 1 describes a general introduction to iodine, hyper-valent ... -
Design and Development of Proteasome Activity Modulators: A Novel Strategy for the Treatment of Diabetes Mellitus
Design and Development of Proteasome Activity Modulators: A Novel Strategy for the Treatment of Diabetes Mellitus Abstract The ubiquitin-proteasome system (UPS) is the major pathway for degradation of the intracellular ... -
Design of Novel NMR Methodologies to address diverse challenging problems in Chemistry
The thesis entitled “Design of Novel NMR Methodologies to address diverse challenging problems in Chemistry” discusses the design of number of novel NMR methodologies which have broader utility and, also the extensive ... -
Design, Synthesis and Optical Characterization of 1,8-Naphthalimide based D-pi-A System
Design, Synthesis and Optical Characterization of 1,8-Naphthalimide based D-pi-A System Luminescent materials find a lot of application in the field of OLEDs and bio-medical applications [1-2]. Our group has recently ... -
Designed Synthesis and Electron Microscopy Investigation of Layered Materials Hybrids for Targeted Applications
Post-discovery and advancement in graphene, the field of layered materials, have gained enormous research interest. These materials have unique and diverse range of properties. Layered materials further provide an opportunity ... -
Determining Functional Parameters of Hybrid Catalysts for Sustainable Energy Storage and Conversion Applications
Generating global-scale sustainable energy systems and preserving our environment for the future at the same time are the biggest challenges. Therefore, the search for diverse energy sources which will reduce our dependency ... -
Development and Evaluation of Plasma Electrolytic Oxidation Coatings for Spacecraft Applications
Spacecraft structures are often fabricated out of light weight materials in order to reduce the overall mass, thereby reducing the launch cost and/or increasing the payload capability. Aluminium alloys, especially AA6061, ... -
Development of novel bionanocomposites for musculoskeletal reconstruction applications
With an increase in the aging population worldwide, a surge in demand for joint replacement has been observed. It has been anticipated that by 2030, the demand for primary total hip joint replacement (THR) will increase ... -
Directing cellular differentiation using biophysical cues on multifunctional biomaterial platforms for neural and osteochondral applications
World health organization (WHO) has recognized multiple degenerative diseases as the leading causes of mortality, globally. The drugs-based clinical treatment of chronic degenerative diseases such as multiple sclerosis, ... -
Diverse Applications of Luminescent Metallocholate Hydrogels
Supramolecular gels are soft materials consisting of a solid three-dimensional network with noncovalent interactions such as hydrophobic interactions, hydrogen bonding, cation-п, and п- п interactions. Due to their soft, ... -
The Effect of Gamma Radiation on Protein Structure and Dynamics
Gamma radiation being the most energetic form of electromagnetic radiation has applications in number of different fields such as in medicine for treating cancer, food sterilization and in astronomy for studying phenomenon ... -
Exploration of Ti-based Anodes for Rechargeable Alkali-ion Batteries And Hybrid-ion Capacitors
From 600 B.C. till 1700 A.D., electricity remained the least understood form of energy and was considered "Magical." In the 18th century A.D., the electricity that mysteriously struck Franklin as he arduously flew a kite ... -
Exploring Topological Phases of Matter using Density Functional Theory and Machine Learning Approaches
Topological phases of matter such as topological insulator (TI), quantum anomalous Hall insulator (QAHI), nodal line semimetal (NLSM), and triple point metal (TPM) can be realized by manipulating the spin-orbit coupling ...